Ring-opening polymerization of cyclohexene oxide using aluminum amine-phenolate complexes

Plommer Hart; Reim Immanuel; Kerton Francesca M.

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Ring-opening polymerization of cyclohexene oxide using aluminum amine-phenolate complexes

机译：使用铝胺-酚盐配合物的环己烯氧化物开环聚合

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Remarkably active (down to 0.001% Al) catalysts for ring-opening polymerization of cyclohexene oxide under neat reaction conditions are reported. High molecular weight polymers with uniform dispersity are produced. Kinetic data from NMR studies and MALDI-TOF MS data of the polymers provide some mechanistic insight.

机译：据报道，在纯净的反应条件下，环氧丙烷的开环聚合反应具有显着活性（低至0.001％Al）。产生具有均匀分散性的高分子量聚合物。 NMR研究的动力学数据和聚合物的MALDI-TOF MS数据提供了一些机理上的见解。

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《Dalton transactions: An international journal of inorganic chemistry》 |2015年第27期|共5页
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Plommer Hart; Reim Immanuel; Kerton Francesca M.;
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1. Ring-opening polymerization of cyclohexene oxide using aluminum amine-phenolate complexes [J] . Plommer Hart, Reim Immanuel, Kerton Francesca M. Dalton transactions: An international journal of inorganic chemistry . 2015,第27期

机译：使用铝胺-酚盐配合物的环己烯氧化物开环聚合
2. Ring-Opening Polymerization of epsilon-Caprolactone and Cyclohexene Oxide Initiated by Aluminum beta-Ketoamino Complexes:Steric and Electronic Effect of 3-Position Substituents of the Ligands [J] . Binyuan Liu, Haiqing Li, Chang-Sik Ha Macromolecular Research . 2008,第5期

机译：β-酮氨基铝配合物引发的ε-己内酯和环己烯氧化物的开环聚合：配体3-位取代基的立体和电子效应
3. Oxo-Bridged Bimetallic Group 4 Complexes Bearing Amine-Bis(benzotriazole phenolate) Derivatives as Bifunctional Catalysts for Ring-Opening Polymerization of Lactide and Copolymerization of Carbon Dioxide with Cyclohexene Oxide [J] . Su Ching-Kai, Chuang Hui-Ju, Li Chen-Yu, Organometallics . 2014,第24期

机译：带有胺-双（苯并三唑酚盐）衍生物的氧桥双金属第4族配合物，作为丙交酯开环聚合和二氧化碳与环己烯氧化物共聚合的双功能催化剂
4. Copolymerization of Cyclohexene Oxide and Carbon Dioxide Catalyzed by Bifunctional Aluminum Porphyrin Complexes [C] . Chihiro Maeda, Hideki Tokuda, Tadashi Ema 日本化学会春季年会講演予稿集 . 2018

机译：双官能铝卟啉配合物催化环己烯和二氧化碳的共聚合
5. Chemistry of Bismuth, Chromium and Magnesium Complexes and Their Applications in the Ring-Opening Polymerization of Cyclic Esters and Epoxides. [D] . Balasanthiran, Vagulejan. 2015

机译：铋，铬和镁配合物的化学及其在环酯和环氧化物的开环聚合中的应用。
6. Ti(IV)–Tris(phenolate) Catalyst Systems for the Ring-Opening Copolymerizationof Cyclohexene Oxide and Carbon Dioxide [O] . SumeshK. Raman, Arron C. Deacy, Leticia Pena Carrodeguas, -1

机译：用于开环共聚的Ti（IV）–Tris（酚盐）催化剂体系环氧乙烷与二氧化碳的合成
7. Ti(IV)–Tris(phenolate) Catalyst Systems for the Ring-Opening Copolymerization of Cyclohexene Oxide and Carbon Dioxide [O] . Sumesh K. Raman, Arron C. Deacy, Leticia Pena Carrodeguas, 2020

机译：用于环己烯和二氧化碳的开环共聚的Ti（IV） - 三（酚酸盐）催化剂体系
8. Preparation and Reactions of Tantalum Alkylidene Complexes Containing Bulky Phenoxide or Thiolate Ligands. Controlling Ring-Opening Metathesis Polymerization Activity and Mechanism Through Choice of Anionic Ligand [R] . Wallace, K. C., Liu, A. H., Dewan, J. C., 1988

机译：含大量酚盐或硫醇盐配体的亚钽基亚砜配合物的制备及反应。通过选择阴离子配体控制开环易位聚合活性及机理

Ring-opening polymerization of cyclohexene oxide using aluminum amine-phenolate complexes

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