Structure and magnetic properties of an unusual homoleptic iron(III) thiocyanate dimer

Dinsdale D. R.; Lough A. J.; Lemaire M. T.

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Structure and magnetic properties of an unusual homoleptic iron(III) thiocyanate dimer

机译：异常均相硫氰酸铁（III）二聚体的结构和磁性

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We describe the structural and variable temperature magnetic susceptibility properties of an unusual homoleptic bimetallic iron(III) thiocyanate tetraanion. This work represents the first structurally characterized bis(mu- 1,3-thiocyanato) dimer of iron(III). A weak antiferromagnetic exchange interaction is observed between the two iron(III) ions, which is supported by broken symmetry density functional theory (DFT) calculations.

机译：我们描述了一种不寻常的均相双金属硫氰酸根四阴离子铁的结构和可变温度磁化率性质。这项工作代表了铁（III）的第一个结构表征的双（μ-1,3-硫氰酸根）二聚体。在两个铁（III）离子之间观察到弱的反铁磁交换相互作用，这由破碎的对称密度泛函理论（DFT）计算得到支持。

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《Dalton transactions: An international journal of inorganic chemistry》 |2015年第24期|共6页
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Dinsdale D. R.; Lough A. J.; Lemaire M. T.;
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1. Structure and magnetic properties of an unusual homoleptic iron(III) thiocyanate dimer [J] . Dinsdale D. R., Lough A. J., Lemaire M. T. Dalton transactions: An international journal of inorganic chemistry . 2015,第24期

机译：异常均相硫氰酸铁（III）二聚体的结构和磁性
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Structure and magnetic properties of an unusual homoleptic iron(III) thiocyanate dimer

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