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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Controllable explosion: fine-tuning the sensitivity of high-energy complexes
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Controllable explosion: fine-tuning the sensitivity of high-energy complexes

机译:可控制的爆炸:微调高能配合物的灵敏度

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摘要

Tuning the sensitivity of energetic materials has always been a research topic of interest. A lot of attention has been paid on changing the ligands previously used in traditional high energy density materials (HEDMs). Recently, we have stepped further along this path by thinking from another angle, i.e., changing the metal centre. Herein, we report 4 transition metal complexes bearing the 1,5-diaminotetrazole ligand, which have similar structures but drastically different sensitivities. These differences are apparently due to the different metal centres used.
机译:调整高能材料的敏感性一直是人们感兴趣的研究课题。在改变以前在传统高能量密度材料(HEDM)中使用的配体方面已经引起了很多关注。最近,我们从另一个角度,即改变金属中心,进一步走了这条路。在此,我们报告了4个带有1,5-二氨基四唑配体的过渡金属配合物,它们具有相似的结构,但敏感性却大不相同。这些差异显然是由于所使用的金属中心不同所致。

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