Reductive dechlorination of BCl3 for efficient ammonia borane regeneration

Tan Yingbin; Zhang Lijun; Chen Xiaowei; Yu Xuebin

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Reductive dechlorination of BCl3 for efficient ammonia borane regeneration

机译：BCl3的还原脱氯以有效地再生氨硼烷

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This paper reports a complete ammonia borane (AB) regeneration process in which Bu3SnH was utilized as a reductant for the reductive dechlorination of BCl3, and Et2PhN was selected as a 'helper ligand' to generate Et2PhN center dot BH3, which gives rise to a high yield of AB by a base-exchange reaction at ambient temperature.

机译：本文报道了一个完整的氨硼烷（AB）再生过程，其中Bu3SnH被用作BCl3的还原脱氯的还原剂，Et2PhN被选作“辅助配体”以生成Et2PhN中心点BH3，从而产生高在室温下通过碱交换反应得到AB的收率。

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《Dalton transactions: An international journal of inorganic chemistry》 |2015年第2期|共5页
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Tan Yingbin; Zhang Lijun; Chen Xiaowei; Yu Xuebin;
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1. Reductive dechlorination of BCl3 for efficient ammonia borane regeneration [J] . Tan Yingbin, Zhang Lijun, Chen Xiaowei, Dalton transactions: An international journal of inorganic chemistry . 2015,第2期

机译：BCl3的还原脱氯以有效地再生氨硼烷
2. Efficient Regeneration of Partially Spent Ammonia Borane Fuel [J] . Benjamin L. Davis, David A. Dixon, Edward B. Garner Angewandte Chemie . 2009,第37期

机译：高效再生部分用过的氨硼烷燃料
3. Superfine CoNi alloy embedded in Al2O3 nanosheets for efficient tandem catalytic reduction of nitroaromatic compounds by ammonia borane [J] . Cheng Sihang, Liu Yanchun, Zhao Yingnan, Dalton transactions: An international journal of inorganic chemistry . 2019,第47期

机译：嵌入Al2O3纳米蛋白酶的超细锥合金，用于通过氨硼烷的高效串联催化还原硝基芳族化合物
4. SYSTEMS MODELING OF AMMONIA BORANE BEAD REACTOR FOR OFF-BOARD REGENERABLE HYDROGEN STORAGE IN PEM FUEL CELL APPLICATIONS [C] . Kriston Brooks, Maruthi Devarakonda, Scot Rassat, ASME International Conference on Fuel Cell Science, Engineering, and Technology . 2010

机译：氨基硼烷珠反应器的系统建模，用于PEM燃料电池应用中的外壳再生储氢
5. New bifunctional catalysts for ammonia-borane dehydrogenation, nitrile reduction, formic acid dehydrogenation, lactic acid synthesis, and carbon dioxide reduction. [D] . Lu, Zhiyao. 2016

机译：用于氨硼烷脱氢，腈还原，甲酸脱氢，乳酸合成和二氧化碳还原的新型双功能催化剂。
6. Ruthenium nanoparticles confined in SBA-15 as highly efficient catalyst for hydrolytic dehydrogenation of ammonia borane and hydrazine borane [O] . Qilu Yao, Zhang-Hui Lu, Kangkang Yang, -1

机译：限制在SBA-15中的钌纳米颗粒作为氨硼烷和肼硼烷的水解脱氢的高效催化剂
7. Efficient Regeneration of Partially Spent Ammonia Borane Fuel [O] . Benjamin L. Davis, David A. Dixon, Edward B. Garner, 2009

机译：有效再生部分废氨硼烷燃料
8. Chemical Hydrogen Storage using Ultra-High Surfgace Area Main Group Materials and the Development of Efficient Amine-Borane Regeneration Cycles. Final Report. [R] . Kauzlarich, S. M., Power, P., Neiner, D., 2010

机译：使用超高冲刷面积主要材料的化学氢储存和高效胺 - 硼烷再生循环的开发。总结报告。

Reductive dechlorination of BCl3 for efficient ammonia borane regeneration

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