Transition metal complex assisted C-sp3-F bond formation

Lin Xiaoxi; Weng Zhiqiang

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Transition metal complex assisted C-sp3-F bond formation

机译：过渡金属配合物辅助C-sp3-F键形成

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Fluoroorganic compounds have attracted significant attention in various fields, such as pharmaceutical, agricultural chemistry, and materials science, as a result of their unique physical, chemical, and physiological properties. Consequently, extensive efforts have been devoted to the site-specific synthesis of organofluorine compounds. In recent years, transition-metal-mediated C-F bond formation has emerged as a powerful method for fabrication of these compounds. This Perspective mainly focuses on the most recent advances in transition-metal-assisted synthesis of alkyl fluorides.

机译：氟有机化合物由于其独特的物理，化学和生理特性，已在制药，农业化学和材料科学等各个领域引起了广泛的关注。因此，已经致力于有机氟化合物的位点特异性合成。近年来，过渡金属介导的C-F键形成已成为制造这些化合物的有力方法。该观点主要集中在过渡金属辅助合成烷基氟化物的最新进展。

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《Dalton transactions: An international journal of inorganic chemistry》 |2015年第5期|共17页
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Lin Xiaoxi; Weng Zhiqiang;
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1. Transition metal complex assisted C-sp3-F bond formation [J] . Lin Xiaoxi, Weng Zhiqiang Dalton transactions: An international journal of inorganic chemistry . 2015,第5期

机译：过渡金属配合物辅助C-sp3-F键形成
2. Theoretical Study on the Transition-Metal Oxoboryl Complex: M–BO Bonding Nature, Mechanism of the Formation Reaction, and Prediction of a New Oxoboryl Complex [J] . Guixiang Zeng and Shigeyoshi Sakaki Inorganic Chemistry . 2012,第8期

机译：过渡金属氧杂硼酸配合物的理论研究：M-BO键的性质，形成反应的机理以及新的氧杂硼酸配合物的预测
3. Functionalization of the C-H Bond of N-Heteroaromatics Assisted by Early Transition-Metal Complexes [J] . Nagae Haruki, Kundu Abhinanda, Inoue Mariko, Asian Journal of Organic Chemistry . 2018,第7期

机译：早期过渡 - 金属配合物辅助N-杂芳烃C-H键的官能化
4. THE ROLE OF METAL-METAL BONDS IN THE FORMATION OF REFRACTORY TRANSITION-METAL PHOSPHIDES AND SULFIDES [C] . H.Fritz Franzen International conference on high temperature materials chemistry . 1997

机译：金属 - 金属键在耐火过渡 - 金属磷酸和硫化物形成中的作用
5. Catalytic Enantioselective Formations of C-B, C-C and C-Si Bonds by Organic Molecules or Transition-Metal Complexes [D] . Wu, Hao 2015

机译：有机分子或过渡金属配合物催化C-B，C-C和C-Si键的对映选择性形成
6. Transition-Metal-Free Formation of C–E Bonds (E = C N O S) and Formation of C–M Bonds (M = Mn Mo) from N-Heterocyclic Carbene Mediated Fluoroalkene C–F Bond Activation [O] . Matthew C. Leclerc, Bulat M. Gabidullin, Jason G. Da Gama, -1

机译：N-杂环碳介导的氟烯烃C-F键活化形成C-E键（E = CNOS）的无过渡金属的形成和C-M键（M = MnMo）的形成
7. C-O Bonds Formation using Transition Metal Alkyl or Aryl Complexes [O] . Jiajun Mei -1

机译：使用过渡金属烷基或芳基复合物形成C-O键形成
8. Bonding Studies of Transition-Metal Complexes. Part II. Helium-1 Photoelectron Spectra of Homoleptic d(0)d(1) and d(10) Tetrakis (Dialkylamides) of Transition and Group 4B Metals and Tungsten Hexakis(Dimethylamide). [R] . Gibbins, S. G., Lappert, M. F., Pedley, J. B., 1974

机译：过渡金属配合物的键合研究。第二部分。 Homoleptic d（0）d（1）和d（10）Tetrakis（二烷基酰胺）的过渡和4B族金属和六氟化钨（二甲基酰胺）的氦-1光电子谱。

Transition metal complex assisted C-sp3-F bond formation

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