Deliberate boxes and accidental wheels

Kaur Gurpreet; Polson Matthew I. J.; Hartshorn Richard M.

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Deliberate boxes and accidental wheels

机译：故意的盒子和意外的轮子

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This report describes systems which combine the structural and reactive motifs of a dinucleating terpyridine-aminomethylpyridine ligand, L, with the coordination preferences and flexibilities of particular divalent metal ions to form a series of closely related box structures in a deliberate fashion. The ligand also produces unprecedented decanickel wheel complexes. Halogen to aromatic hydrogen interactions may be important in stabilising the decanickel wheel structures.

机译：该报告描述了将二核化的吡啶-氨基甲基吡啶配体L的结构和反应性基序与特定二价金属离子的配位偏好和柔韧性结合在一起，以有意方式形成一系列紧密相关的盒结构的系统。该配体还产生了前所未有的癸铜轮络合物。卤素与芳族氢的相互作用对于稳定izing镍轮结构可能很重要。

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《Dalton transactions: An international journal of inorganic chemistry》 |2015年第9期|共7页
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Kaur Gurpreet; Polson Matthew I. J.; Hartshorn Richard M.;
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1. Deliberate boxes and accidental wheels [J] . Kaur Gurpreet, Polson Matthew I. J., Hartshorn Richard M. Dalton transactions: An international journal of inorganic chemistry . 2015,第9期

机译：故意的盒子和意外的轮子
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