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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >De facto methodologies toward the synthesis and scale-up production of UiO-66-type metal-organic frameworks and membrane materials
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De facto methodologies toward the synthesis and scale-up production of UiO-66-type metal-organic frameworks and membrane materials

机译：UiO-66型金属有机骨架和膜材料的合成和大规模生产的实际方法

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摘要

Metal-organic frameworks (MOFs) are architected via coordination bonds between inorganic metal nodes and organic ligands. They have become emerging advanced porous materials and gained ever-increasing attention in the past decade. In particular, overwhelming studies have been devoted to those hydrostable MOFs which are suggested to be highly promising for industrial applications. UiO-66 is such a unique MOF because of its superior thermal/chemical stability and structural tunability. However, its repeatable, green, and scale-up synthesis remains a challenge for its commercialization and implementation in industrial applications. This perspective mainly summarises the recent development in the synthesis of UiO-66-type MOFs and their related composites. From a scale-up viewpoint, we also present some important advances in the batch and continuous reactor synthesis toward their massive production (226 references).
机译：金属有机框架（MOF）是通过无机金属节点与有机配体之间的配位键设计的。在过去的十年中，它们已成为新兴的高级多孔材料，并受到越来越多的关注。特别是，对那些对工业应用具有高度希望的水稳性MOF进行了大量研究。 UiO-66之所以如此独特，是因为其卓越的热/化学稳定性和结构可调性。然而，其可重复，绿色和按比例放大的合成对其商业化和在工业应用中的实施仍然是一个挑战。该观点主要总结了UiO-66型MOF及其相关复合材料合成的最新进展。从放大的角度来看，我们还介绍了分批和连续反应器合成朝着大规模生产的重要进展（参考文献226）。

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