Dinuclear first-row transition metal complexes with a naphthyridine-based dinucleating ligand

Davenport T. C.; Tilley T. D.

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Dinuclear first-row transition metal complexes with a naphthyridine-based dinucleating ligand

【24h】

Dinuclear first-row transition metal complexes with a naphthyridine-based dinucleating ligand

机译：具有基于萘啶的双核配体的双核第一行过渡金属配合物

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A series of dinuclear and tetranuclear first-row transition metal complexes were synthesized with the dinucleating ligand 2,7-bis(di(2-pyridyl) fluoromethyl)-1,8-naphthyridine (DPFN). The coordination pocket and rigidity of the DPFN ligand enforces pseudo-octahedral geometries about the metal centers that contain chloro, hydroxo, and aqua bridging ligands forming a "diamond" shaped configuration with metal-metal distances varying from 2.7826(5) to 3.2410(11) angstrom. Each metal center in the dinuclear complexes has an additional open coordination site that accommodates terminal ligands in a syn geometry of particular interest in catalyst design. The complexes are characterized by electronic spectroscopy, electrochemistry and potentiometric titration methods.

机译：用双核配体2,7-双（二（2-吡啶基）氟甲基）-1,8-萘啶（DPFN）合成了一系列双核和四核第一行过渡金属配合物。 DPFN配位体的配位口袋和刚性在包含氯，羟基和水桥配位体的金属中心周围形成伪八面体几何形状，从而形成“菱形”形构型，金属与金属之间的距离从2.7826（5）到3.2410（11）不等）埃。双核络合物中的每个金属中心都有一个额外的开放配位位点，该位点可以在催化剂设计中特别关注的顺式几何结构中容纳末端配体。配合物通过电子光谱，电化学和电位滴定法表征。

著录项

来源
《Dalton transactions: An international journal of inorganic chemistry》 |2015年第27期|共12页
作者
Davenport T. C.; Tilley T. D.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词

相似文献

外文文献
中文文献
专利

1. Dinuclear first-row transition metal complexes with a naphthyridine-based dinucleating ligand [J] . Davenport T. C., Tilley T. D. Dalton transactions: An international journal of inorganic chemistry . 2015,第27期

机译：具有基于萘啶的双核配体的双核第一行过渡金属配合物
2. Coordination chemistry of Robson-type polyamine-dithiophenolate macrocycles: Syntheses, structures and magnetic properties of dinuclear complexes of first-row transition metals [J] . Vasile Lozan, Claudia Loose, Jens Kortus, Coordination chemistry reviews . 2009,第19a20期

机译：Robson型多胺-二硫代酚酸酯大环的配位化学：第一行过渡金属双核配合物的合成，结构和磁性
3. Synthesis of a novel dinucleating aminocarboxylate macrocycle and structures of its dinuclear complexes with di- and trivalent transition and lanthanide metal ions [J] . Brunner J, Pritzkow H, Kramer R Dalton transactions: An international journal of inorganic chemistry . 2005,第2期

机译：新型二核氨基羧酸盐大环化合物的合成及其具有二价和三价过渡和镧系元素金属离子的双核配合物的结构
4. PNNN (3-pyridyl-5-diphenylphosphmomethylpyrazolate):a novel versatile dinucleating ligand. Reversible metal migration in the Ir-PNNN system,selective formation of isomeric heterodiunuclear complexes and the study of their reactivitiy [C] . Christian Dubs, Akiko Inagaki, Munetaka Akita Symposium on Organometallic Chemistry . 2004

机译：PNNN（3-吡啶基-5-二苯基膦酰基甲基吡唑酸酯）：一种新型多功能二核配体。 IR-PNNN系统中可逆金属迁移，选择性地形成异构异二核核复合物及其反应的研究
5. Reactions of First-Row Transition Metal Complexes in Bis(Alkoxide) Ligand Environments with Diazoalkanes: Formation of Carbenes Versus Reductive Coupling to Form Bridging Tetrazenes [D] . ?Grass, Amanda 2020

机译：二烷烷烃的双（醇盐）配体环境中的一排过渡金属配合物的反应：形成碳酸盐与还原偶联以形成桥接四斋
6. Synthesis of a Redox-Active NNP-Type Pincer Ligand and Its Application to Electrocatalytic CO2 Reduction With First-Row Transition Metal Complexes [O] . Kallol Talukdar, Asala Issa, Jonah W. Jurss 1970

机译：具有氧化还原活性的NNP型钳型配体的合成及其在第一行过渡金属配合物电催化还原CO2中的应用
7. Complexes of Aminosquarate Ligands with First-Row Transition Metals and Lanthanides: New Insights into Their Hydrolysis [O] . -1

机译：氨基齐全配体的复合物，具有一排过渡金属和镧系元素：新的洞察力进入水解
8. Polytertiary Phosphines and Arsines. 19. Some First-Row Transition Metal Chloride Complexes of Ditertiary and Tritertiary Phosphines Containing Terminal Methoxy Groups [R] . King, R. B., Bibber, J. W. 1981

机译：聚三氟膦和胂。 19.含有末端甲氧基的二叔和叔膦的第一排过渡金属氯化物配合物

Dinuclear first-row transition metal complexes with a naphthyridine-based dinucleating ligand

摘要

著录项

相似文献

相关主题

期刊订阅