Stoichiometric and catalytic Si-N bond formation using the p-block base Al(NMe2)(3)

Allen Lucy K.; Garcia-Rodriguez Raul; Wright Dominic S.

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Stoichiometric and catalytic Si-N bond formation using the p-block base Al(NMe2)(3)

机译：使用p嵌段碱Al（NMe2）（3）形成化学计量和催化作用的Si-N键

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The aluminium amide Al(NMe2)(3) acts as a stoichiometric or catalytic reagent in dehydrogenic Si-N bond formation using amines and silanes. Although of limited substrate scope, this represents the first p-block metal catalytic system for N-H/Si-H dehydrocoupling. The observed catalytic rate law for the formation of aminosilane products in a model study of one of the catalytic reactions suggests a mechanism involving the silane component in the deprotonation of the amine (possibly in the form of a hypervalent silicon hydride).

机译：铝酰胺Al（NMe2）（3）在使用胺和硅烷的脱水Si-N键形成过程中充当化学计量或催化试剂。尽管受衬底范围的限制，但这代表了用于N-H / Si-H脱氢偶联的第一个p嵌段金属催化体系。在对一种催化反应的模型研究中，观察到的形成氨基硅烷产物的催化速率定律表明，一种机理涉及在胺的去质子化中涉及硅烷组分（可能以高价氢化硅的形式）。

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《Dalton transactions: An international journal of inorganic chemistry》 |2015年第27期|共7页
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Allen Lucy K.; Garcia-Rodriguez Raul; Wright Dominic S.;
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1. Stoichiometric and catalytic Si-N bond formation using the p-block base Al(NMe2)(3) [J] . Allen Lucy K., Garcia-Rodriguez Raul, Wright Dominic S. Dalton transactions: An international journal of inorganic chemistry . 2015,第27期

机译：使用p嵌段碱Al（NMe2）（3）形成化学计量和催化作用的Si-N键
2. Activation of alkyl C-F Bonds by B(C _6F _5) _3: Stoichiometric and catalytic transformations [J] . Caputo C.B., Stephan D.W. Organometallics . 2012,第1期

机译：通过B（C _6F _5）_3活化烷基C-F键：化学计量和催化转化
3. Activation of alkyl C-F Bonds by B(C _6F _5) _3: Stoichiometric and catalytic transformations [J] . Caputo C.B., Stephan D.W. Organometallics . 2012,第1期

机译：通过B（C _6F _5）_3活化烷基C-F键：化学计量和催化转化
4. Development of Catalytic C-C Bond Formation Based on Addition of Metal Enolates to Unsaturated Hydrocarbons [C] . Kohei Endo, Masaharu Nakamura, Eiichi Nakamura Symposium on Organometallic Chemistry . 2004

机译：基于加入金属烯丙基烯丙基酯的催化C-C键形成的研制
5. Base-Promoted Stoichiometric Alkyl Carbon-Halogen Bond Cleavage and Catalytic Hydrodehalogenation with Water by Rhodium Porphyrins and Iodine-Catalyzed Carbon-Carbon σ-Bond Hydrogenation with Water [D] . Yang, Wu. 2018

机译：通过铑卟啉和碘催化的碳 - 碳Σ - 致水与水的水基促进化学计量烷基卤素碳 - 卤素粘膜和催化力加氢钠
6. Efficient Access to Multifunctional Trifluoromethyl Alcohols via Base-free Catalytic Asymmetric C-C Bond Formation with Terminal Ynamides [O] . Andrea M. Cook, Christian Wolf -1

机译：通过无碱催化不对称C-C键与末端酰胺形成多功能三氟甲基醇
7. Stoichiometric and catalytic Si–N bond formation using the p-block base Al(NMe2)3 [O] . Allen Dominic Simon, Garcia-Rodriguez Raul, Wright Dominic S 2015

机译：使用p嵌段碱Al（NMe2）3的化学计量和催化Si–N键形成

Stoichiometric and catalytic Si-N bond formation using the p-block base Al(NMe2)(3)

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