Argentivorous molecules bearing three aromatic side arms: synthesis of triple-armed cyclens and their complexing property towards Ag+

Habata Yoichi; Kizaki Juli; Hosoi Yasuhiro; Ikeda Mari; Kuwahara Shunsuke

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Argentivorous molecules bearing three aromatic side arms: synthesis of triple-armed cyclens and their complexing property towards Ag+

机译：带有三个芳族侧链的精油分子：三臂式细胞周期蛋白的合成及其对Ag +的络合特性

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Triple-armed cyclens bearing three aromatic side-arms were prepared in three steps from (3R,5S)-3,5-dimethyl-1,4,7,10-tetraazacyclododecane-2,6-dione, and the Ag+-ion-induced H-1 NMR and UV-vis spectral changes and X-ray structures suggested that the aromatic side-arms cover the Ag+ incorporated into the ligand cavities like an insectivorous plant (Venus flytrap).

机译：从（3R，5S）-3,5-二甲基-1,4,7,10-四氮杂环十二烷-2,6-二酮和Ag +-离子-的三个步骤中制备了带有三个芳族侧臂的三臂环诱导的H-1 NMR和UV-vis光谱变化以及X射线结构表明，芳族侧臂覆盖了掺入配体腔中的Ag +，就像食虫植物（维纳斯捕蝇器）一样。

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《Dalton transactions: An international journal of inorganic chemistry》 |2015年第3期|共8页
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Habata Yoichi; Kizaki Juli; Hosoi Yasuhiro; Ikeda Mari; Kuwahara Shunsuke;
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1. Argentivorous molecules bearing three aromatic side arms: synthesis of triple-armed cyclens and their complexing property towards Ag+ [J] . Habata Yoichi, Kizaki Juli, Hosoi Yasuhiro, Dalton transactions: An international journal of inorganic chemistry . 2015,第3期

机译：带有三个芳族侧链的精油分子：三臂式细胞周期蛋白的合成及其对Ag +的络合特性
2. Synthesis of luminescent homo-dinuclear cationic lanthanide cyclen complexes bearing amide pendant arms through the use of copper catalysed(1,3-Huisgen, CuAAC) click chemistry [J] . Jennifer K. Molloy, Oxana Kotova, Robert D. Peacock, Organic & biomolecular chemistry . 2012,第2期

机译：通过铜催化的（1,3-Huisgen，CuAAC）点击化学合成具有酰胺侧基臂的发光均核阳离子镧系元素周期化合物
3. Toxic metal complexes of macrocyclic cyclen molecule - synthesis, structure and complexing properties [J] . Litecka M., Gyepes R., Vargova Z., Journal of Coordination Chemistry . 2017,第9a10期

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4. Efficient Synthesis and Photochromic Properties of a New Diarylethene Bearing a Condensed Aromatics Moiety [C] . Renjie Wang, Hongying Xia, Gang Liu, SSITE International Conference on Future Material Research and Industry Application . 2012

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5. Cucurbit[n]uril host -guest complexes: The effects of inclusion on the chemical reactivity and spectroscopic properties of aromatic guest molecules [D] . Wang, Ruibing 2007

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6. Synthesis Complexation Properties and Evaluation of New Aminodiphosphonic Acids as Vector Molecules for 68Ga Radiopharmaceuticals [O] . Alesya Ya. Maruk, Valery V. Ragulin, Iurii A. Mitrofanov, 2021

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7. 1H NMR Study of a Chiral Argentivorous Molecule/Ag+ Complex: Assignment of Proton Signals of Four Aromatic Rings with Slightly Different Environments [O] . -1

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8. Synthesis and Properties of Three Triple-Armed Amphipiles [R] . Menger, F. M., deGreiff, A. J. A., Jaeger, D. A. 1984

机译：三种三臂船的合成与性能

Argentivorous molecules bearing three aromatic side arms: synthesis of triple-armed cyclens and their complexing property towards Ag+

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