POSS as building-blocks for the preparation of polysilsesquioxanes through an innovative synthetic approach

Marchesi Stefano; Carniato Fabio; Palin Luca; Boccaleri Enrico

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POSS as building-blocks for the preparation of polysilsesquioxanes through an innovative synthetic approach

机译：POSS作为通过创新的合成方法制备聚倍半硅氧烷的基础

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A novel solvent-free solid-state synthesis was used to prepare a non-crystalline polysilsesquioxane sample, with a peculiar viscous form. The material was synthesized through direct self-condensation of a partially condensed polyhedral oligomeric silsesquioxane (POSS) and its physico-chemical properties, in terms of composition/structure, thermal stability and hydrophobicity, were investigated.

机译：一种新颖的无溶剂固态合成用于制备具有特殊粘性形式的非晶态聚倍半硅氧烷样品。该材料是通过部分缩合的多面体低聚倍半硅氧烷（POSS）的直接自缩合合成的，并研究了其理化性质，包括组成/结构，热稳定性和疏水性。

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《Dalton transactions: An international journal of inorganic chemistry》 |2015年第5期|共5页
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Marchesi Stefano; Carniato Fabio; Palin Luca; Boccaleri Enrico;
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POSS as building-blocks for the preparation of polysilsesquioxanes through an innovative synthetic approach

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