Synthesis and magnetic properties of tartrate-bridging rare-earth-containing polytungstoarsenate aggregates from an adaptive precursor [As2W19O67( H2O)](14-)

Wang Yuan; Sun Xiaopeng; Li Suzhi; Ma Pengtao; Wang Jingping; Niu Jingyang

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Synthesis and magnetic properties of tartrate-bridging rare-earth-containing polytungstoarsenate aggregates from an adaptive precursor [As2W19O67( H2O)](14-)

机译：适应性前体[As2W19O67（H2O）]（14-）的酒石酸桥含稀土多钨砷酸盐聚集体的合成和磁性

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Six tartrate-bridging rare-earth-substituted polytungstoarsenates [RE2(C4H4O6)(C4H2O6)(As W9O33)](2)(18-)( Ho-III (1), Er-III (2), Tm-III (3), Yb-III (4), Lu-III (5), and Y-III (6)) have been synthesized under conventional solution conditions. They have been further characterized by elemental analyses, X-ray powder diffraction (XRPD), IR and UV-vis spectroscopy and single-crystal X-ray diffraction. Preliminary variable-temperature magnetic susceptibility measurements indicate that 1-4 exhibit antiferromagnetic coupling.

机译：六种酒石酸桥稀土取代的多钨砷酸盐[RE2（C4H4O6）（C4H2O6）（As W9O33）]（2）（18-）（Ho-III（1），Er-III（2），Tm-III（3 ），Yb-III（4），Lu-III（5）和Y-III（6））是在常规溶液条件下合成的。它们的特征还在于元素分析，X射线粉末衍射（XRPD），IR和UV可见光谱以及单晶X射线衍射。初步的可变温度磁化率测量表明1-4具有反铁磁耦合。

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《Dalton transactions: An international journal of inorganic chemistry》 |2015年第2期|共6页
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Wang Yuan; Sun Xiaopeng; Li Suzhi; Ma Pengtao; Wang Jingping; Niu Jingyang;
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1. Synthesis and magnetic properties of tartrate-bridging rare-earth-containing polytungstoarsenate aggregates from an adaptive precursor [As2W19O67( H2O)](14-) [J] . Wang Yuan, Sun Xiaopeng, Li Suzhi, Dalton transactions: An international journal of inorganic chemistry . 2015,第2期

机译：适应性前体[As2W19O67（H2O）]（14-）的酒石酸桥含稀土多钨砷酸盐聚集体的合成和磁性
2. Preparation, characterization, and catalytic performances of a pyrazine dicarboxylate-bridging rare-earth-containing polytungstoarsenate aggregate for selective oxidation of thiophenes and deep desulfurization of model fuels [J] . Niu Yanjun, Xu Qiaofei, Wang Yuan, Dalton transactions: An international journal of inorganic chemistry . 2018,第29期

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机译：团簇间相互作用对（Cr3O（CH3COO）6（H2O）3）Cl-6H2O的热和磁性能的影响。

Synthesis and magnetic properties of tartrate-bridging rare-earth-containing polytungstoarsenate aggregates from an adaptive precursor [As2W19O67( H2O)](14-)

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