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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >First three-dimensional actinide polyrotaxane framework mediated by windmill-like six-connected oligomeric uranyl: dual roles of the pseudorotaxane precursor
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First three-dimensional actinide polyrotaxane framework mediated by windmill-like six-connected oligomeric uranyl: dual roles of the pseudorotaxane precursor

机译:风车状六连接低聚铀酰介导的第一个三维act系元素聚轮烷骨架:假轮烷前体的双重作用

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摘要

The first 3D actinide polyrotaxane framework (named IHEP-URCP-2) has been obtained based on windmill-like six-connected high-nuclear oligomeric uranyl nodes under hydrothermal conditions. Notably, the in situ formed pseudorotaxane ligand simultaneously plays dual roles of both a bulky pseudorotaxane linker and a supramolecular guest.
机译:第一个3D wind系元素聚轮烷骨架(名为IHEP-URCP-2)是在水热条件下基于风车状六连接的高核低聚铀酰节点获得的。值得注意的是,原位形成的假轮烷配体同时扮演了庞大的假轮烷接头和超分子客体的双重角色。

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