Preparation of pyranylidene complexes of ruthenium

Albertin Gabriele; Antoniutti Stefano; Bortoluzzi Marco; Botter Alessandra; Castro Jesus

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Preparation of pyranylidene complexes of ruthenium

机译：钌的亚吡咯烷配合物的制备

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The reaction of the chloro-complex RuCl(eta(5)-C5H5)(PPh3)[P(OMe)(3)] with alkylpropiolates HC equivalent to CCOOR1 in alcohol R2OH affords pyranylidene derivatives [Ru(eta(5)-C5H5){=C(COOR1)C(H)C(H)C(OR1)O}(PPh3){ P(OMe)(3)}]BPh4 (1, 3) and alkoxycarbene complexes [Ru(eta(5)-C5H5){=C(OR2)(CH(2)COOR1)}(PPh3){P(OMe)(3)}]BPh4 (2, 4). A reaction path for the formation of compounds 1-4, involving reactions on a vinylidene intermediate complex, is also discussed. The complexes were characterized spectroscopically (IR and H-1, C-13, P-31 NMR) and by X-ray crystal structure determination of [Ru(eta(C5H5)-C-5){=C(COOMe)C(H)C(H)C(OMe)O}(PPh3){P(OMe)(3)}] BPh4 (1).

机译：氯配合物RuCl（eta（5）-C5H5）（PPh3）[P（OMe）（3）]与相当于CCOOR1的烷基丙酸酯HC在醇R2OH中的反应得到吡喃亚烷基衍生物[Ru（eta（5）-C5H5） {= C（COOR1）C（H）C（H）C（OR1）O}（PPh3）{P（OMe）（3）}] BPh4（1、3）和烷氧基卡宾配合物[Ru（eta（5）- C5H5）{= C（OR2）（CH（2）COOR1）}（PPh3）{P（OMe）（3）}] BPh4（2，4）。还讨论了形成化合物1-4的反应路径，该反应路径涉及在亚乙烯基中间配合物上的反应。对该络合物进行光谱表征（IR和H-1，C-13，P-31 NMR）并通过X射线晶体结构测定[Ru（eta（C5H5）-C-5）{= C（COOMe）C（ H）C（H）C（OMe）O}（PPh3）{P（OMe）（3）}] BPh4（1）。

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《Dalton transactions: An international journal of inorganic chemistry》 |2015年第16期|共8页
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Albertin Gabriele; Antoniutti Stefano; Bortoluzzi Marco; Botter Alessandra; Castro Jesus;
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1. Preparation of pyranylidene complexes of ruthenium [J] . Albertin Gabriele, Antoniutti Stefano, Bortoluzzi Marco, Dalton transactions: An international journal of inorganic chemistry . 2015,第16期

机译：钌的亚吡咯烷配合物的制备
2. New synthetic routes for the preparation of ruthenium-1,10-phenanthroline complexes. Tests of cytotoxic and antibacterial activity of selected ruthenium complexes. [J] . Iztok Turel, Amalija Golobi?, Jakob Kljun, Acta Chimica Slovenica . 2015,第2期

机译：制备钌1,10-菲咯啉配合物的新合成途径。所选钌配合物的细胞毒性和抗菌活性测试。
3. Preparation, stability, and photoreactivity of thiolato ruthenium polypyridyl complexes: Can cysteine derivatives protect ruthenium-based anticancer complexes? [J] . van Rixel Vincent H. S., Busemann Anja, Gottle Adrien J., Journal of Inorganic Biochemistry: An Interdisciplinary Journal . 2015,第Null期

机译：硫醇基钌多吡啶基复合物的制备，稳定性和光反应性：半胱氨酸衍生物可以保护基于钌的抗癌复合物吗？
4. One-step couplig between polypyridine metal complexes: preparation of rigid and dendritic nano-sized ruthenium complexes [C] . Masahisa Osawa, Mikio Hoshino, Shigeo Horiuchi, The Third SANKEN international symposium on advanced nanoelectronics : Devices, materials, and computing . 2000

机译：聚吡啶金属配合物之间的一步一步修饰：刚性和树枝状纳米级钌配合物的制备
5. THE PREPARATION AND REACTIONS OF SOME GROUP-VIII METAL COMPLEXES. PART I: THE REACTION OF TRIVALENT PENTAAMMINENITROSYL RUTHENIUM WITH HYDROXIDE ION. PART II: PREPARATION AND REACTIONS OF HALOBIS (ORTHO- PHENYLENEBISDIMETHYL ARSINE)NITROSYLOSMIUM COMPLE [D] . KIREMIRE, ENOS MASHEIJA RWANTALE. 1977

机译：某些VIII族金属络合物的制备和反应。第一部分：三价戊氨基亚硝酰钌与氢氧根离子的反应。第二部分：卤代亚砜（邻苯二甲撑二甲基A基）硝基亚砜的制备与反应
6. Preparation Spectrochemical and Computational Analysis of L-Carnosine (2-(3-Aminopropanoyl)amino-3-(1H-imidazol-5-yl)propanoic Acid) and Its Ruthenium (II) Coordination Complexes in Aqueous Solution [O] . Michael Lee Branham, Parvesh Singh, Krishna Bisetty, 2011

机译：左旋肌氨酸（2-（3-氨基丙酰基）氨基 -3-（1H-咪唑-5-基）丙酸）及其水溶液中钌（II）配位化合物的制备光谱化学和计算分析
7. Preparation of Pyranylidene Complexes of Ruthenium [O] . G. Albertin, S. Antoniutti, M. Bortoluzzi, 2015

机译：钌的吡喃亚烷基配合物的制备
8. Chemically Significant Interactions Between Ruthenium Ions in Oxo-Bridged Complexes of Ruthenium(III). [R] . Weaver, T. R., Meyer, T. J., Adeyemi, A., 1974

机译：钌（III）羰基桥联配合物中钌离子之间的化学显着相互作用。

Preparation of pyranylidene complexes of ruthenium

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