Polyoxova nadate-based organic inorganic hybrids: from {V5O9Cl} clusters to nanosized octahedral cagest

Zhang Yu-Teng; Wang Xin-Long; Zhou En-Long; Wu Xue-Song; Song Bai-Qiao; Shao Kui-Zhan; Su Zhong-Min

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Polyoxova nadate-based organic inorganic hybrids: from {V5O9Cl} clusters to nanosized octahedral cagest

机译：聚氧萘磺酸盐基有机无机杂化物：从{V5O9Cl}簇到纳米八面体笼型

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Three polyoxovanadate-based metal -organic polyhedra (denoted as VMOP-1, -2, and -3), adopting isostructural discrete octahedral cage geometries, were successfully synthesized under solvothermal conditions. These structures are all built up from the same pentavanadate (V5O9Cl cluster connected by linear bidentate ligands (H(2)L1 = H2BDC, H(2)L2 = H2BDC-NH2, H(2)L3 = H2BDC-Br), respectively.

机译：在溶剂热条件下成功地合成了三种基于等氧杂酸盐的金属-有机多面体（分别表示为VMOP-1，-2和-3），这些结构采用等结构的离散八面体笼形结构。这些结构均由相同的五钒酸盐（通过线性双齿配体连接的V5O9Cl簇（H（2）L1 = H2BDC，H（2）L2 = H2BDC-NH2，H（2）L3 = H2BDC-Br）构建而成。

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《Dalton transactions: An international journal of inorganic chemistry》 |2016年第9期|共4页
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Zhang Yu-Teng; Wang Xin-Long; Zhou En-Long; Wu Xue-Song; Song Bai-Qiao; Shao Kui-Zhan; Su Zhong-Min;
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1. Polyoxova nadate-based organic inorganic hybrids: from {V5O9Cl} clusters to nanosized octahedral cagest [J] . Zhang Yu-Teng, Wang Xin-Long, Zhou En-Long, Dalton transactions: An international journal of inorganic chemistry . 2016,第9期

机译：聚氧萘磺酸盐基有机无机杂化物：从{V5O9Cl}簇到纳米八面体笼型
2. Sensitization of Er~(3+) Infrared Photoluminescence Embedded in a Hybrid Organic-Inorganic Copolymer containing Octahedral Molybdenum Clusters [J] . Yann Molard, Christophe Labbe, Julien Cardin, Advanced Functional Materials . 2013,第38期

机译：含八面体钼团簇的有机-无机杂化共聚物中嵌入的Er〜（3+）红外光致敏
3. Intrinsic Yellow Light Phosphor: An Organic-Inorganic Hybrid Gallium Oxalatophosphate with Hexameric Octahedral Ga_6(OH)_4O_(26) Cluster [J] . Ya-Ching Yang, Sue-Lein Wang Journal of the American Chemical Society . 2008,第4期

机译：固有的黄光磷光体：具有六聚八面体Ga_6（OH）_4O_（26）簇的有机-无机杂化草酸镓镓。
4. SYNTHESIS AND CHARACTERIZATION OF NANOCOMPOSITES COATING BASED ON INORGANIC OCTAHEDRAL CLUSTER UNITS FABRICATED BY ELECTROPHORETIC DEPOSITION PROCESS [C] . Fabien Grasset, Ngan. T. K. Nguyen, Adele Renaud, International Conference on Electrophoretic Deposition: Fundamentals and Applications . 2018

机译：基于电泳沉积工艺制造的无机八面体簇单元的纳米复合材料涂层的合成与表征
5. From molecular tinkertoys to inorganic-organic hybrid composites - functional materials featuring metal chalcogenide clusters. [D] . Roland, Bryan Kruger. 2003

机译：从分子修补匠到无机-有机杂化复合材料-具有金属硫族化物簇的功能材料。
6. Significance of hydrogen bonding and other noncovalent interactions in determining octahedral tilting in the CH3NH3PbI3 hybrid organic-inorganic halide perovskite solar cell semiconductor [O] . Pradeep R. Varadwaj, Arpita Varadwaj, Helder M. Marques, -1

机译：氢键和其他非共价相互作用在确定CH3NH3PbI3杂化有机-无机卤化物钙钛矿太阳能电池半导体中八面体倾斜中的意义
7. Sensitization of Er 3 + Infrared Photoluminescence Embedded in a Hybrid Organic-Inorganic Copolymer containing Octahedral Molybdenum Clusters [O] . Molard, Yann, Labbé, Christophe, Cardin, Julien, 2013

机译：嵌入八面体钼团簇的有机-无机杂化共聚物中嵌入的Er 3 +红外光致敏化
8. Synthesis, Processing, and Characterization of Inorganic-Organic Hybrid Cross-Linked Silica, Organic Polyimide, and Inorganic Aluminosilicate Aerogels. [R] . Nguyen, B. N., Guo, H. N., McCorkle, L. S. 2014

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Polyoxova nadate-based organic inorganic hybrids: from {V5O9Cl} clusters to nanosized octahedral cagest

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