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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Two novel pillared-layer lanthanide borates built by Ln@B12O28/29 ring clusters and dicarboxylate linkers (Ln = Pr, Nd)
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Two novel pillared-layer lanthanide borates built by Ln@B12O28/29 ring clusters and dicarboxylate linkers (Ln = Pr, Nd)

机译:由Ln @ B12O28 / 29环簇和二羧酸盐连接基(Ln = Pr,Nd)构建的两种新型柱状镧系硼酸盐

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摘要

Two organic-inorganic hybrid pillared-layer lanthanide borates, [Ln(2)B(8)O(12)(bdc)(3)(H2O)]center dot H2O (Ln = Pr, 1; Nd, 2; H(2)bdc = 1,4-benzene dicarboxylic acid), have been made, in which inorganic layers are built by Ln-centred oxoboron ring clusters, Ln@B12O28/Ln@B12O29, while the pillars are organic bdc linkers. Interestingly, two types of linkages, Ln-O-C and B-O-C bonds, exist in the structures, showing firstly novel linking modes between inorganic polyborate and organic dicarboxylate.
机译:两种有机-无机杂化柱状镧系元素硼酸盐[Ln(2)B(8)O(12)(bdc)(3)(H2O)]中心点H2O(Ln = Pr,1; Nd,2; H( 2)bdc = 1,4-苯二甲酸),其中无机层是由以Ln为中心的氧杂硼酸环簇Ln @ B12O28 / Ln @ B12O29构建的,而支柱是有机bdc接头。有趣的是,结构中存在两种类型的键,即Ln-O-C和B-O-C键,首先显示了无机多硼酸酯和有机二羧酸酯之间的新型连接方式。

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