A novel open-framework copper borophosphate containing 1-D borophosphate anion with 10-MR windows and 12-MR channels

Feng Yuquan; Li Min; Fan Huitao; Huang Qunzeng; Qiu Dongfang; Shi Hengzhen

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A novel open-framework copper borophosphate containing 1-D borophosphate anion with 10-MR windows and 12-MR channels

机译：一种新颖的开放式骨架含1D硼磷酸根阴离子的硼硼酸铜，具有10-MR窗口和12-MR通道

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A novel open-framework copper borophosphate, Na5KCu3[B9P6O33( OH)(3)]center dot H2O (1), has been synthesised by a boric acid flux method. Its structure can be viewed as a 3-D open framework constructed by the connection of (CuO6)-O-II octahedra and 1-D (4,4)-connected borophosphate anionic structures composed of trigonal-planar BO2(OH) groups, tetrahedral BO4 and PO4 groups. The compound not only features a novel borophosphate anionic partial structure containing 1-D 12-MR channels, but also exhibits ferromagnetic interactions and high catalytic activity for the oxidative degradation of chitosan.

机译：通过硼酸助熔剂法合成了一种新型的开放骨架的硼磷酸铜Na5KCu3 [B9P6O33（OH）（3）]中心点H2O（1）。它的结构可以看作是由（CuO6）-O-II八面体与1-D（4,4）连接的由三角平面BO2（OH）基组成的硼磷酸盐阴离子结构连接而构成的3-D开放框架，四面体BO4和PO4组。该化合物不仅具有包含1-D 12-MR通道的新型硼磷酸盐阴离子部分结构，而且还具有铁磁相互作用和对壳聚糖氧化降解的高催化活性。

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《Dalton transactions: An international journal of inorganic chemistry》 |2015年第3期|共4页
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Feng Yuquan; Li Min; Fan Huitao; Huang Qunzeng; Qiu Dongfang; Shi Hengzhen;
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1. A novel open-framework copper borophosphate containing 1-D borophosphate anion with 10-MR windows and 12-MR channels [J] . Feng Yuquan, Li Min, Fan Huitao, Dalton transactions: An international journal of inorganic chemistry . 2015,第3期

机译：一种新颖的开放式骨架含1D硼磷酸根阴离子的硼硼酸铜，具有10-MR窗口和12-MR通道
2. The molten hydrated flux synthesis of a novel open-framework copper borophosphate and its structural relation with the precursors [J] . Long Zhao, Wei Liu, Xiaohong Ma, Journal of Solid State Chemistry . 2014,第Null期

机译：新型开骨架硼酸铜的熔融水合助熔剂合成及其与前体的结构关系
3. LiCu_2[BP_2O_8(OH)_2]: A chiral open-framework copper borophosphate via spontaneous asymmetrical crystallization [J] . Yang M., Li X., Yu J., Dalton transactions: An international journal of inorganic chemistry . 2013,第18期

机译：LiCu_2 [BP_2O_8（OH）_2]：通过自发不对称结晶形成的手性开放骨架硼磷酸铜
4. An open-framework borophosphate LiCu2BP2O8(OH)2 [O] . Juan Zheng, Aiyun Zhang 2009

机译：开放框架的硼磷酸盐LiCu2BP2O8（OH）2
5. A new borophosphate chain anion in an organo-templated iron(III)borophosphate: Synthesis, crystal structure and magnetic properties of (C₄H₁₂N₂)₃Fe₆^III(H₂O)₄[B₆P₁₂O₅₀(OH)₂] • 2H₂O [O] . Huang, Y., Prots, Y., Schnelle, W., 2007

机译：有机模板化铁（III）硼磷酸盐中新的硼磷酸链阴离子：（C _{4 H _{12 N _{2 的合成，晶体结构和磁性子>）<子> 3 铁<子> 6 ^{III （H <子> 2 O）<子> 4 [B _{6 p _{12 O _{50 （OH）_{2 ]•2H _{2 O}}}}}}}}}

A novel open-framework copper borophosphate containing 1-D borophosphate anion with 10-MR windows and 12-MR channels

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