Synthesis and characterisation of thioether functionalised gallium and indium alkoxides

Barth Sven; Biegger Felix; Puchberger Michael

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Synthesis and characterisation of thioether functionalised gallium and indium alkoxides

机译：硫醚官能化的镓和铟的醇盐的合成与表征

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This paper provides evidence of formerly unknown thioether coordination in metal alkoxides. The thioether functionalised alkanols serving as alcoholate ligands have been prepared by a generic route. The gallium and indium alkoxides provide the first evidence for sulphur coordination in the liquid and solid state in metal alkoxide derivatives. The presence of amines suppresses the coordination of thioether moieties leading to a well-known bonding mode in aminoalcoholates.

机译：本文提供了以前未知的金属醇盐中硫醚配位的证据。已经通过通用途径制备了用作醇化物配体的硫醚官能化的链烷醇。镓和铟的醇盐为金属醇盐衍生物中液态和固态的硫配位提供了第一个证据。胺的存在抑制了硫醚部分的配位，从而导致氨基醇酸酯中众所周知的键合模式。

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《Dalton transactions: An international journal of inorganic chemistry》 |2015年第37期|共7页
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Barth Sven; Biegger Felix; Puchberger Michael;
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1. Synthesis and characterisation of thioether functionalised gallium and indium alkoxides [J] . Barth Sven, Biegger Felix, Puchberger Michael Dalton transactions: An international journal of inorganic chemistry . 2015,第37期

机译：硫醚官能化的镓和铟的醇盐的合成与表征
2. Electrochemical synthesis and characterisation of gallium, indium and thallium compounds with 1-hydroxopyridine-2-thione. The crystal structures of tris(1-oxopyridine-2-thionato)indium(III) and tris(1-oxopyridine-2-thionato)thallium(III) [J] . Rodriguez A., Garcia-Vazquez JA., Sousa A., Inorganica Chimica Acta . 1998,第1期

机译：1-羟基氧吡啶-2-硫酮的镓，铟和al化合物的电化学合成和表征。三（1-氧吡啶-2-硫代）铟（III）和三（1-氧吡啶-2-硫代）al（III）的晶体结构
3. Effect of In-C-NHC Bonds on the Synthesis, Structure, and Reactivity of Dialkylindium Alkoxides: How Indium Compares to Gallium [J] . Cybularczyk Martyna, Dranka Maciej, Zachara Janusz, Organometallics . 2016,第19期

机译：In-C-NHC键对二烷基铟醇盐的合成，结构和反应性的影响：铟与镓的比较
4. Design of Characterisation of an Indium Gallium Arsenide Multiple Quantum Web Modulator Operating with 5 Volts [C] . Byrne, D., Horan, . 2001

机译：5伏工作的砷化铟镓多量子网络调制器的表征设计
5. Synthesis, Characterisation and Application of Some Functionalised Supramolecules. [D] . Gupte, Hrishikesh S. 2011

机译：某些功能化超分子的合成，表征和应用。
6. Aerosol-assisted CVD of thioether-functionalised indium aminoalkoxides [O] . Felix Biegger, Felix Jungwirth, Michael Stanislaus Seifner, -1

机译：硫醚官能化铟氨基醇盐的气溶胶辅助CVD
7. Thioether functionalised gallium and indium alkoxides in materials synthesis [O] . Felix Biegger, Christoph Rameshan, Alexander K. Opitz, 2016

机译：硫醚官能化镓和材料合成中铟醇盐

Synthesis and characterisation of thioether functionalised gallium and indium alkoxides

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