Enantiopure and racemic radical-cation salts of B(malate)(2)(-) anions with BEDT-TTF

Lopez Jordan R.; Martin Lee; Wallis John D.; Akutsu Hiroki; Nakazawa Yasuhiro; Yamada Jun-ichi; Kadoya Tomofumi; Coles Simon J.; Wilson Claire

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Enantiopure and racemic radical-cation salts of B(malate)(2)(-) anions with BEDT-TTF

机译：B（苹果酸）（2）（-）阴离子与BEDT-TTF的对映体和外消旋自由基阳离子盐

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We have synthesized the first examples of radical-cation salts of BEDT-TTF with chiral borate anions, [B(malate)(2)](-), prepared from either enantiopure or racemic bidentate malate ligands. In the former case only one of two diastereoisomers of the borate anion is incorporated, while for the hydrated racemic salt one racemic pair of borate anions containing a R and a S malate ligand is incorporated. Their conducting and magnetic properties are reported. The tight-binding band calculation indicates that the chiral salt has an effective half-filled flat band, which is likely to be caused by the chiral structural feature.

机译：我们已经合成了手性硼酸根阴离子[B（苹果酸）（2）]（-）与BEDT-TTF的阳离子阳离子盐的第一个实例，它们是从对映体纯或外消旋二齿苹果酸配体制备的。在前一种情况下，仅掺入硼酸根阴离子的两个非对映异构体之一，而对于水合外消旋盐，掺入一对外消旋对的含R和S苹果酸配体的硼酸根阴离子。报告了它们的导电和磁性。紧密结合带计算表明手性盐具有有效的半填充平坦带，这很可能是由手性结构特征引起的。

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《Dalton transactions: An international journal of inorganic chemistry》 |2016年第22期|共9页
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Lopez Jordan R.; Martin Lee; Wallis John D.; Akutsu Hiroki; Nakazawa Yasuhiro; Yamada Jun-ichi; Kadoya Tomofumi; Coles Simon J.; Wilson Claire;
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1. Enantiopure and racemic radical-cation salts of B(malate)(2)(-) anions with BEDT-TTF [J] . Lopez Jordan R., Martin Lee, Wallis John D., Dalton transactions: An international journal of inorganic chemistry . 2016,第22期

机译：B（苹果酸）（2）（-）阴离子与BEDT-TTF的对映体和外消旋自由基阳离子盐
2. Chiral Radical-Cation Salts of BEDT-TTF Containing a Single Enantiomer of Tris(oxalato)aluminate(III) and -chromate(III) [J] . Martin Lee, Akutsu Hiroki, Horton Peter N., European journal of inorganic chemistry . 2015,第11期

机译：BEDT-TTF的手性自由基阳离子盐，含三（草酸）铝酸盐（III）和-铬酸盐（III）的单一对映体
3. Radical-cation salt with novel BEDT-TTF packing motif containing tris (oxalato)germanate(IV) [J] . Lopez Jordan R., Akutsu Hiroki, Martin Lee Synthetic Metals . 2015,第Null期

机译：具有新型BEDT-TTF包装基序的自由基阳离子盐，含三（草酸）锗酸（IV）
4. Electrical and Spectral Properties of Organic Salts Formed from BEDT-TTF and Magnetic Anions [C] . Andrzej Graja, Andrzej Lapinski, Vladimir A. Starodub International Conference on Electrical and Related Properties of Organic Solids . 2004

机译：由卧床-TTF和磁阴离子形成的有机盐的电气和光谱性能
5. Synthesis of Racemic and Enantiopure Samples of Zearalenone [D] . Blechman, Scotty L. 2019

机译：玉米赤霉烯酮外消旋和对映纯样品的合成
6. A new compound in the BEDT-TTF family BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene with a tetrathiocyanatocuprate(II) anion (BEDT-TTF)4Cu(NCS)4 [O] . Christophe Faulmann, Benoît Cormary, Lydie Valade, 2018

机译：BEDT-TTF家族中的一种新化合物BEDT-TTF =双（乙基二烯二硫基）四噻吩富勒烯与四硫氰酸氰基酸盐（II）阴离子（BEDT-TTF）4 Cu（NCS）4
7. Enantiopure and racemic radical-cation salts of B(malate)2-anions with BEDT-TTF [O] . Lopez Jordan R., Martin Lee, Wallis John D., 2016

机译：B（苹果酸）2-阴离子与BEDT-TTF的对映纯度和外消旋自由基阳离子盐
8. Importance of weak hydrogen bonding C-H--donor and C-H--anion interactions in governing the structural properties of organic donors BEDT-TTF and BEDO-TTF and their charge-transfer salts. [R] . Whangbo, M. H., Jung, D., Ren, J., 1989

机译：弱氢键C-H - 供体和C-H - 阴离子相互作用在控制有机供体BEDT-TTF和BEDO-TTF及其电荷转移盐的结构性质中的重要性。

Enantiopure and racemic radical-cation salts of B(malate)(2)(-) anions with BEDT-TTF

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