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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >A novel oxime-derived 3d-4f single-molecule magnet exhibiting two single-ion magnetic relaxations
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A novel oxime-derived 3d-4f single-molecule magnet exhibiting two single-ion magnetic relaxations

机译:一种新颖的肟衍生的3d-4f单分子磁体,具有两个单离子磁弛豫

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摘要

A new oxime-derived {(Dy4Ni6II)-Ni-III} cluster with a paramagnetic butterfly-shaped Dy-4(III) core and peripheral diamagnetic planar-square Ni-II ions was solvothermally synthesized. The weak ferromagnetically coupled cluster exhibits field-induced single-molecule magnetic behavior with two thermally activated single-ion relaxations.
机译:溶剂热合成了新的肟衍生的{(Dy4Ni6II)-Ni-III}团簇,该团簇具有顺磁性蝶形Dy-4(III)核和周围的反磁性平面正方形Ni-II离子。弱铁磁耦合簇具有两个热激活单离子弛豫的场诱导单分子磁行为。

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