Activation of A-H bonds (A = B, C, N, O, Si) by using monovalent phosphorus complexes [RP -  M]

Mathey Francois; Duan Zheng

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Activation of A-H bonds (A = B, C, N, O, Si) by using monovalent phosphorus complexes [RP - M]

机译：通过使用一价磷络合物激活A-H键（A = B，C，N，O，Si）[RP-> M]

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The available data on the activation of A-H sigma bonds by electrophilic terminal phosphinidene complexes are reviewed. Theoretical computations allow us to rationalize the experimental results. It appears that a successful insertion needs an initial interaction between the phosphinidene and the A-H bond, such as a donor-acceptor complex with a lone pair, a Coulombic interaction due to a negative charge on A or H, or a proximity effect.

机译：审查了有关亲电的次膦亚基络合物活化A-Hσ键的可用数据。理论计算使我们能够合理化实验结果。似乎成功的插入需要在次膦基和A-H键之间进行初始相互作用，例如具有孤对的供体-受体复合物，由于A或H上的负电荷引起的库仑相互作用或邻近效应。

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《Dalton transactions: An international journal of inorganic chemistry》 |2016年第5期|共6页
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Mathey Francois; Duan Zheng;
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1. Activation of A-H bonds (A = B, C, N, O, Si) by using monovalent phosphorus complexes [RP - M] [J] . Mathey Francois, Duan Zheng Dalton transactions: An international journal of inorganic chemistry . 2016,第5期

机译：通过使用一价磷络合物激活A-H键（A = B，C，N，O，Si）[RP-> M]
2. White phosphorus activation at a metal-phosphorus triple bond: A new route to cyclo-triphosphorus or cyclo-pentaphosphorus complexes of niobium [J] . Tofan D., Cossairt B.M., Cummins C.C. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2011,第24期

机译：金属-磷三键处的白磷活化：铌的环三磷或环五磷络合物的新途径
3. Isomerization of Secondary Phosphirane into Terminal Phosphinidene Complexes: An Analogy between Monovalent Phosphorus and Transition Metals [J] . Wong Jonathan, Li Yongxin, Hao Yanwei, Angewandte Chemie . 2015,第44期

机译：次膦烷异构化为末端膦亚胺配合物：一价磷与过渡金属之间的类比
4. Activation of Polarized Single Bonds by Complexes Having an Iron-Silicon-Phosphorus Linkage [C] . Kveone A Jung, Masaaki Okazaki, Hiromi Tobita Symposium on Organometallic Chemistry . 2003

机译：通过具有铁 - 硅 - 磷键的复合物激活偏振单键
5. Investigating the C–H Bond Activation Mechanism at Phosphorus(V) Oxides Using Vanadium Phosphorus Oxide (VPO) Model Complexes [D] . Carroll, Timothy Gary. 2020

机译：使用钒磷氧化物（VPO）模型配合物研究磷（V）氧化物的C-H键活化机制
6. A designed second-sphere hydrogen-bond interaction that critically influences the O–O bond activation for heterolytic cleavage in ferric iron–porphyrin complexes [O] . Sarmistha Bhunia, Atanu Rana, Somdatta Ghosh Dey, 2020

机译：设计的第二球形氢键相互作用对铁卟鸡卟啉复合物中的o-o键活化进行致密地影响O-O键活化
7. A designed second-sphere hydrogen-bond interaction that critically influences the O–O bond activation for heterolytic cleavage in ferric iron–porphyrin complexes [O] . Sarmistha Bhunia, Atanu Rana, Somdatta Ghosh Dey, 2020

机译：设计的第二球形氢键相互作用，对铁卟鸡卟啉复合物中的o-o键活化进行致密地影响O-O键活化

Activation of A-H bonds (A = B, C, N, O, Si) by using monovalent phosphorus complexes [RP - M]

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