Synthesis of a new class of silsesquioxanes with alkynyl and germyl functionality

Rzonsowska M.; Dudziec B.; Marciniec B.

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Synthesis of a new class of silsesquioxanes with alkynyl and germyl functionality

机译：新型的具有炔基和胚芽官能度的倍半硅氧烷的合成

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Although there are a variety of functional compounds in the vast family of silsesquioxanes (POSS), the number of protocols describing specific monosubstituted silsesquioxanes is limited. There are even fewer reports on alkynyl and/or germyl functionalities appearing together with the POSS compounds. Here, a series of novel kinds of cubic monosubstituted POSS bearing alkynyl and germyl functionality in one molecule are reported. These compounds were synthesized by effective germylative coupling of terminal alkynes with vinylgermanes in the presence of a Ru-H complex. The structures of the products were determined. Moreover, stoichiometric reactions of a complex possessing Ru-Ge were also performed to propose the general mechanistic scheme of this reaction.

机译：尽管在庞大的倍半硅氧烷（POSS）系列中有多种功能化合物，但是描述特定单取代倍半硅氧烷的方案数量有限。关于炔基和/或胚芽官能度与POSS化合物一起出现的报道甚至更少。在此，报道了一系列在一个分子中带有炔基和芽基官能团的新型立方单取代的POSS。这些化合物是通过在Ru-H络合物存在下，末端炔烃与乙烯基锗烷进行有效的萌芽偶联而合成的。确定了产品的结构。此外，还进行了具有Ru-Ge的配合物的化学计量反应，以提出该反应的一般机理。

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《Dalton transactions: An international journal of inorganic chemistry》 |2016年第43期|共8页
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Rzonsowska M.; Dudziec B.; Marciniec B.;
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1. Synthesis of a new class of silsesquioxanes with alkynyl and germyl functionality [J] . Rzonsowska M., Dudziec B., Marciniec B. Dalton transactions: An international journal of inorganic chemistry . 2016,第43期

机译：新型的具有炔基和胚芽官能度的倍半硅氧烷的合成
2. Functionalized alkynyl-chlorogermanes: hydrometallation, Ge-Cl bond activation, Ge-H bond formation and chlorine-tert-butyl exchange via a transient germyl cation [J] . Honacker Christian, Qu Zheng-Wang, Tannert Jens, Dalton transactions: An international journal of inorganic chemistry . 2016,第14期

机译：功能化的炔基-氯锗烷：加氢金属化，Ge-Cl键活化，Ge-H键形成和通过短暂的胚芽阳离子交换氯-叔丁基
3. Lithiation of 1-alkynyl-1-chlorocyclopropanes and subsequent reactions with electrophilic reagents: synthesis of functionalized alkynyl- and vinylidenecyclopropanes [J] . Gvozdev V. D., Shavrin K. N., Nefedov O. M. Russian Chemical Bulletin . 2019,第7期

机译：1-炔基-1-氯环丙烷的锂化和随后用电泳试剂的反应：官能化炔基和乙烯基丁丙烷的合成
4. Utilization of Chelated Germyl Enolates toward Synthesis of Functionalized Compounds: Diastereoselective Aldol Reaction and Transformation of Germanium-Carbon Bond [C] . Yohei Minami, Akihito Konishi, Makoto Yasuda 日本化学会春季年会講演予稿集 . 2018

机译：利用螯合衍生物掺入官能化化合物的合成：非对映选择性醛醇反应和锗 - 碳键的转化
5. Routes to Silsesquioxanes Functionalization: Capping of DDSQs for the Synthesis of Asymmetric POSS Compounds [D] . Barry, Badru-Deen. 2019

机译：到Silsesquioxanes官能化的路线：用于合成不对称POSS化合物的DDSQ的封盖
6. Synthesis of Silsesquioxanes with Substituted Triazole Ring Functionalities and Their Coordination Ability [O] . Monika Rzonsowska, Katarzyna Kozakiewicz, Katarzyna Mituła, 2021

机译：具有取代的三唑环功能的Silsesquioxanes的合成及其协调能力
7. Synthesis and Hydrosilylation of Vinyl-Substituted Open-Cage Silsesquioxanes with Phenylsilanes: Regioselective Synthesis of Trifunctional Silsesquioxanes [O] . Magdalena Grzelak, Rafał Januszewski, Bogdan Marciniec 2020

机译：苯基硅烷乙烯基 - 取代的乙烯基 - 取代的开放式静脉氧化镁的合成与氢化硅烷化：三官能氧化硅氧烷的区域选择性合成
8. Polyhedral Oligomeric Silsesquioxane-Functionalized Perfluorocyclobutyl Aryl Ether Polymers: An Overview of the Synthesis and Properties of Polyhedral Oligomeric Silsesquioxanes (POSS) Functionalized with Perfluorocyclobutyl (PFCB) Aryl Ether Polymer Ble [R] . Iacono, S. T., Budy, S. M., Smith, J. D., 2007

机译：多面体低聚倍半硅氧烷 - 官能化全氟环丁基芳基醚聚合物：用全氟环丁基（pFCB）芳基醚聚合物共聚物功能化的多面体低聚倍半硅氧烷（pOss）的合成和性质概述

Synthesis of a new class of silsesquioxanes with alkynyl and germyl functionality

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