Iron cyclopentadienone complexes derived from C-2-symmetric bis-propargylic alcohols; preparation and applications to catalysis

Hodgkinson Roy; Del Grosso Alessandro; Clarkson Guy; Wills Martin

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Iron cyclopentadienone complexes derived from C-2-symmetric bis-propargylic alcohols; preparation and applications to catalysis

机译：衍生自C-2-对称双炔丙醇的环戊二烯酮铁配合物;的制备及其在催化中的应用

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A series of complexes containing the iron-cyclopentadienone structure were prepared by cyclising bis-propargylic alcohols and their derivatives with iron pentacarbonyl. The resulting complexes were characterised and tested in the catalysis of ketone reduction and alcohol oxidation. The complexes are competent catalysts for ketone reduction and alcohol oxidations.

机译：通过将双炔丙醇及其衍生物与五羰基铁环化，制备了一系列含有铁-环戊二烯酮结构的配合物。在催化酮还原和醇氧化反应中对所得的配合物进行了表征和测试。该络合物是用于酮还原和醇氧化的有效催化剂。

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《Dalton transactions: An international journal of inorganic chemistry》 |2016年第9期|共14页
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Hodgkinson Roy; Del Grosso Alessandro; Clarkson Guy; Wills Martin;
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1. Iron cyclopentadienone complexes derived from C-2-symmetric bis-propargylic alcohols; preparation and applications to catalysis [J] . Hodgkinson Roy, Del Grosso Alessandro, Clarkson Guy, Dalton transactions: An international journal of inorganic chemistry . 2016,第9期

机译：衍生自C-2-对称双炔丙醇的环戊二烯酮铁配合物;的制备及其在催化中的应用
2. Synthesis of (R)-BINOL-Derived (Cyclopentadienone)iron Complexes and Their Application in the Catalytic Asymmetric Hydrogenation of Ketones [J] . Gajewski Piotr, Renom-Carrasco Marc, Facchini Sofia Vailati, European journal of organic chemistry . 2015,第25期

机译：（R）-联醇衍生的（环戊二烯酮）铁配合物的合成及其在酮催化不对称加氢中的应用
3. Synthesis of an electron-rich KITPHOS monophosphine, preparation of derived metal complexes and applications in catalysis [J] . Doherty S., Smyth C.H., Knight J.G., Nature protocols erecipes for researchers . 2012,第10期

机译：富电子的KITPHOS单膦的合成，衍生的金属配合物的制备及其在催化中的应用
4. Synthesis of new complexes for the alcohol dehydrogenation reaction andthe sulfonylation of alcohols via dehydrogenation catalysis [C] . Eugene Khaskin, Shubham Deolka, Saiyyna Stepanova 日本化学会春季年会 . 2020

机译：通过脱氢催化合成醇脱氢反应的新配合物和醇的硫化物
5. IRON AND RUTHENIUM COMPLEXES POSSESSING UNUSUAL ELECTRONIC PROPERTIES. PART I: SYNTHESIS AND SPIN STATE STUDIES OF GAMMA-SUBSTITUTED TRIS(BETA-DIKETONATO)IRON(III) COMPLEXES AND THEIR BETA-KETOIMINE ANALOGUES DERIVED FROM TRIETHYLENETETRAMINE. PART II: A DIRECT MEASUREMENT OF DYNAMIC SPIN INTERCONVERSION RATES IN THE SPIN EQUILIBRIUM PROTEIN FERRIC MYOGLOBIN HYDROXIDE. PART III: SYNTHESIS, PHOTOEMISSION, AND ELECTROCHEMICAL STUDIES OF. [D] . DOSE, ERIC VON. 1978

机译：铁和钌络合物具有异常的电子特性。第一部分：γ-取代的三（三乙酮）铁（III）配合物及其三乙胺丁胺类似物的β-酮亚胺类似物的合成和自旋态研究。第二部分：纺丝平衡蛋白三水合肌红蛋白中动态纺丝互变速率的直接测量。第三部分：的合成，光生化和电化学研究。
6. Cyclopentadienone Iron Alcohol Complexes: Synthesis Reactivity and Implications for the Mechanism of Iron Catalyzed Hydrogenation of Aldehydes [O] . Charles P. Casey, Hairong Guan -1

机译：环戊二烯酮铁醇配合物：醛的铁催化加氢反应机理的合成反应性和意义。
7. Iron cyclopentadienone complexes derived from C2-symmetric bis-propargylic alcohols; preparation and applications to catalysis [O] . Hodgkinson, Roy, Del Grosso, Alessandro, Clarkson, Guy J., 2016

机译：衍生自C2-对称双炔丙醇的环戊二烯酮铁配合物；的制备及其在催化中的应用

Iron cyclopentadienone complexes derived from C-2-symmetric bis-propargylic alcohols; preparation and applications to catalysis

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