Iodosylbenzene and iodylbenzene adducts of cerium(IV) complexes bearing chelating oxygen ligands

Au-Yeung Ka-Chun; So Yat-Ming; Wang Guo-Cang; Sung Herman H. -Y.; Williams Ian D.; Leung Wa-Hung

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Iodosylbenzene and iodylbenzene adducts of cerium(IV) complexes bearing chelating oxygen ligands

机译：带有螯合氧配体的铈（IV）配合物的碘基苯和碘基苯加合物

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Reactions of [Ce-IV(L-OEt)(2)Cl-2] (L-OEt(-)= [Co(eta(5)-C5H5){P(O)(OEt)(2)}(3)](-)) and [Ce-2(IV) (mu-O){N((Pr2PO)-P-i)(2)}(4)Cl-2] with PhIO afford the lambda(3)-iodane complexes [Ce-IV(L-OEt)(2){OI(Cl) Ph}(2)] and [CeIV2 {N(Pri(2)PO)(2)}(3){OI(Cl) Ph}], respectively, whereas that between [CeIV(L-OEt)(2)Cl-2] and PhIO2 or excess PhIO yields the lambda(5)-iodane adduct [CeIV(L-OEt)(2){OI(O) ClPh}(2)]. The crystal structures of the Ce-IV lambda(3)-and lambda(5)-iodane complexes have been determined and their oxo transfer reactivities have been investigated.

机译：[Ce-IV（L-OEt）（2）Cl-2]的反应（L-OEt（-）= [Co（eta（5）-C5H5）{P（O）（OEt）（2）}（3 ）]（-））和[Ce-2（IV）（mu-O）{N（（Pr2PO）-Pi）（2）}（4）Cl-2]与PhIO提供lambda（3）-碘络合物[Ce-IV（L-OEt）（2）{OI（Cl）Ph}（2）]和[CeIV2 {N（Pri（2）PO）（2）}（3）{OI（Cl）Ph}] ，而[CeIV（L-OEt）（2）Cl-2]和PhIO2之间或过量的PhIO则产生λ（5）-碘加合物[CeIV（L-OEt）（2）{OI（O）ClPh }（2）]。 Ce-IV lambda（3）和lambda（5）-碘配合物的晶体结构已确定，并已研究了它们的羰基转移反应性。

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《Dalton transactions: An international journal of inorganic chemistry》 |2016年第13期|共5页
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Au-Yeung Ka-Chun; So Yat-Ming; Wang Guo-Cang; Sung Herman H. -Y.; Williams Ian D.; Leung Wa-Hung;
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1. Iodosylbenzene and iodylbenzene adducts of cerium(IV) complexes bearing chelating oxygen ligands [J] . Au-Yeung Ka-Chun, So Yat-Ming, Wang Guo-Cang, Dalton transactions: An international journal of inorganic chemistry . 2016,第13期

机译：带有螯合氧配体的铈（IV）配合物的碘基苯和碘基苯加合物
2. Synthetic Models of the Active Site of Cytochrome c Oxidase;Influence of Tridentate or Tetradentate Copper Chelates Bearing a His-Tyr Linkage Mimic on Dioxygen Adduct Formation by Heme/Cu Complexes [J] . Jin-Gang Liu, Yoshinori Naruta, Fumito Tani Chemistry: A European journal . 2007,第22期

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3. Synthetic Models of the Active Site of Cytochrome c Oxidase;Influence of Tridentate or Tetradentate Copper Chelates Bearing a His-Tyr Linkage Mimic on Dioxygen Adduct Formation by Heme/Cu Complexes [J] . Jin-Gang Liu, Yoshinori Naruta, Fumito Tani Chemistry: A European journal . 2007,第22期

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机译：来自非血脂（IV）复合物和铈（III）的钢（III） - 氧化铈（IV）加合物的耐铁（III） - 氧化铈（IV）的容易和可逆形成

Iodosylbenzene and iodylbenzene adducts of cerium(IV) complexes bearing chelating oxygen ligands

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