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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Ferromagnetic coupling mediated by Co center dot center dot center dot pi non-covalent contacts in a pentacoordinate Co(II) compound showing field-induced slow relaxation of magnetization
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Ferromagnetic coupling mediated by Co center dot center dot center dot pi non-covalent contacts in a pentacoordinate Co(II) compound showing field-induced slow relaxation of magnetization

机译:五配位Co(II)化合物中Co中心点中心点中心点pi非共价接触介导的铁磁耦合,显示磁场诱导的磁化缓慢弛豫

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摘要

[Co-II(dpt)(NCS)(2)], where dpt = bis(3-aminopropyl)amine, was identified as a pentacoordinate Co-II compound showing field-induced slow relaxation of magnetization. Furthermore, intermolecular ferromagnetic coupling mediated by Co center dot center dot center dot pi non-covalent contacts, where pi orbitals originate from the thiocyanato ligand, is reported for the first time.
机译:[Co-II(dpt)(NCS)(2)],其中dpt =双(3-氨基丙基)胺,被确定为五配位Co-II化合物,显示出磁场诱导的磁化缓慢弛豫。此外,首次报道了由Co中心点中心点中心点pi非共价接触介导的分子间铁磁耦合,其中π轨道起源于硫氰酸根配体。

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