Silver(I), gold(I) and palladium(II) complexes of a NHC-pincer ligand with an aminotriazine core: a comparison with pyridyl analogues

Vaughan Jamila; Carter Damien J.; Rohl Andrew L.; Ogden Mark I.; Skelton Brian W.; Simpson Peter V.; Brown David H.

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Silver(I), gold(I) and palladium(II) complexes of a NHC-pincer ligand with an aminotriazine core: a comparison with pyridyl analogues

机译：NHC钳式配体与氨基三嗪核的银（I），金（I）和钯（II）配合物：与吡啶类似物的比较

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Dinuclear silver, di- and tetra-nuclear gold, and mononuclear palladium complexes with chelating C, N, C diethylaminotriazinyl-bridged bis(NHC) pincer ligands were prepared and characterised. The silver and gold complexes exist in a twisted, helical conformation in both the solution-and the solid state. In contrast, an analogous dinuclear gold complex with pyridyl-bridged NHCs exists in a linear conformation. Computational studies have been performed to rationalise the formation of twisted/helical vs. linear forms.

机译：制备并表征了具有螯合C，N，C二乙氨基三嗪基桥联的双（NHC）钳位配体的双核银，双核和四核金以及单核钯配合物。银和金络合物在溶液和固态中均以扭曲的螺旋构型存在。相反，具有吡啶基桥联的NHC的类似的双核金络合物以线性构象存在。已经进行了计算研究以使扭曲/螺旋与线性形式的形成合理化。

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《Dalton transactions: An international journal of inorganic chemistry》 |2016年第4期|共12页
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Vaughan Jamila; Carter Damien J.; Rohl Andrew L.; Ogden Mark I.; Skelton Brian W.; Simpson Peter V.; Brown David H.;
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1. Silver(I), gold(I) and palladium(II) complexes of a NHC-pincer ligand with an aminotriazine core: a comparison with pyridyl analogues [J] . Vaughan Jamila, Carter Damien J., Rohl Andrew L., Dalton transactions: An international journal of inorganic chemistry . 2016,第4期

机译：NHC钳式配体与氨基三嗪核的银（I），金（I）和钯（II）配合物：与吡啶类似物的比较
2. Synthesis, structural characterization, solution behavior, and in vitro antiproliferative properties of a series of gold complexes with 2-(2′-pyridyl)benzimidazole as ligand: Comparisons of gold(III) versus gold(I) and mononuclear versus binuclear derivatives [J] . Serratrice M., Cinellu M.A., Maiore L., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2012,第5期

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3. Synthesis of palladium(II) complexes with 3-amino-5-methyl-5-(4-pyridyl)-hydantoin: cytotoxic and antimicrobial investigations and comparison with their platinum analogues [J] . H. Varbanov, A. Bakalova, R. Buyukliev Transition Metal Chemistry . 2010,第4期

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4. A Comparative Study Of A Series Of Dimethylgold(III) Complexes With S,S Chelating Ligands Used As MOCVD Precursors [C] . Asiya Turgambaeva, Roman Parkhomenko, Vladimir Aniskin, European Conference on Chemical Vapour Deposition . 2013

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机译：纳米球光刻：I.大面积银纳米颗粒阵列的制造和表征。二。银纳米粒子尺寸的电化学调节。三，银，金，钴，钯和铂纳米粒子的纳米粒子形状随尺寸变化。
6. Structural and Luminescent Properties of HomolepticSilver(I) Gold(I) and Palladium(II) Complexes with nNHC-tzNHC Heteroditopic Carbene Ligands [O] . Marco Monticelli, Marco Baron, Cristina Tubaro, 2019

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7. Silver(i), gold(i) and palladium(ii) complexes of a NHC-pincer ligand with an aminotriazine core: a comparison with pyridyl analogues [O] . Jamila Vaughan, Damien J. Carter, Andrew L. Rohl, 2016

机译：NHC-iner配体的银（I），金（I）和钯（II）复合物，其具有氨管氧核：与吡啶基类似物的比较

Silver(I), gold(I) and palladium(II) complexes of a NHC-pincer ligand with an aminotriazine core: a comparison with pyridyl analogues

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