A novel 3D energetic MOF of high energy content: synthesis and superior explosive performance of a Pb(II) compound with 5,5 '-bistetrazole-1,1 '-diolate

Shang Yu; Jin Bo; Peng Rufang; Liu Qiangqiang; Tan Bisheng; Guo Zhicheng; Zhao Jun; Zhang Qingchun

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A novel 3D energetic MOF of high energy content: synthesis and superior explosive performance of a Pb(II) compound with 5,5 '-bistetrazole-1,1 '-diolate

机译：高能量含量的新型3D能量MOF：具有5,5'-双四唑-1,1'-二醇盐的Pb（II）化合物的合成和优异的爆炸性能

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The development of high-performance insensitive energetic materials is important because of the increasing demand for these materials in military and civilian applications. A novel 3D energetic metal-organic framework (MOF) of exceptionally high energy content, [Pb(BTO)(H2O)](n), was synthesized and structurally characterized by single crystal X-ray diffraction, featuring a three-dimensional parallelogram porous framework, where BTO represents 5,5'-bistetrazole-1,1'-diolate. The thermal stability and energetic properties were determined, exhibiting good thermostability (T-d = 309.0 degrees C), excellent detonation pressure (P) of 53.06 GPa, a detonation velocity (D) of 9.204 km s(-1), and acceptable sensitivity to confirmed impact (IS = 7.5 J). Notably, the complex possesses unprecedented superior density than the reported energetic MOFs. The results highlight this new MOF as a potential energetic material.

机译：高性能不敏感的高能材料的开发非常重要，因为在军事和民用应用中对这些材料的需求不断增长。合成了一种具有极高能量含量的新型3D高能金属有机骨架（MOF）[Pb（BTO）（H2O）]（n），并通过单晶X射线衍射对其结构进行了表征，其特征是三维平行四边形多孔框架，其中BTO代表5,5'-双四唑-1,1'-二醇盐。确定了热稳定性和高能性能，表现出良好的热稳定性（Td = 309.0摄氏度），优异的起爆压力（P）为53.06 GPa，起爆速度（D）为9.204 km s（-1），并且对确定的敏感性冲击（IS = 7.5 J）。值得注意的是，该复合物比报道的高能MOF具有前所未有的优越密度。结果突出了这种新的MOF作为潜在的能量材料。

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《Dalton transactions: An international journal of inorganic chemistry》 |2016年第35期|共7页
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Shang Yu; Jin Bo; Peng Rufang; Liu Qiangqiang; Tan Bisheng; Guo Zhicheng; Zhao Jun; Zhang Qingchun;
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1. A novel 3D energetic MOF of high energy content: synthesis and superior explosive performance of a Pb(II) compound with 5,5 '-bistetrazole-1,1 '-diolate [J] . Shang Yu, Jin Bo, Peng Rufang, Dalton transactions: An international journal of inorganic chemistry . 2016,第35期

机译：高能量含量的新型3D能量MOF：具有5,5'-双四唑-1,1'-二醇盐的Pb（II）化合物的合成和优异的爆炸性能
2. Crystal structure evolution of an energetic compound dihydroxylammonium 5,5 '-bistetrazole-1,1 '-diolate induced by solvents [J] . Xu Xin, Chen Dong, Li Hongzhen, RSC Advances . 2020,第20期

机译：通过溶剂诱导的高能复合二羟基铵5,5'-苄唑-1,1' - 溶剂的晶体结构演变
3. Crystal structure evolution of an energetic compound dihydroxylammonium 5,5′-bistetrazole-1,1′-diolate induced by solvents [J] . Xin Xu, Dong Chen, Hongzhen Li, RSC Advances . 2020,第20期

机译：溶剂诱导的溶剂诱导的能量化合物二羟基铵5,5'-双四唑-1,1'-二氢醇的晶体结构演变
4. Effluent Treatment Approaches Generated During Synthesis of Dihydroxyl Ammonium 5,5'-Bistetrazole 1,1'-Diolate (TKX-50) [C] . Kiran S KULKARN, Dilip M BADGUJAR, Desai B SARWADE, Beijing Institute of Technology;China Ordnance Society;International autumn seminar on propellants, explosives and pyrotechnics;Hubei Institute of Aerospace Chemotechnology . 2015

机译：合成5,5'-二噻唑1,1'-二碘酸盐二羟基铵（TKX-50）时产生的污水处理方法
5. Synthesis, characterization and energetic performance of metal boride compounds for insensitive energetic materials [D] . Whittaker, Michael L. 2012

机译：不敏感高能材料中金属硼化物的合成，表征和高能性能
6. Voltammetric Determination of Pb(II) by a Ca-MOF-Modified Carbon Paste Electrode Integrated in a 3D-Printed Device [O] . Evaggelia Vlachou, Antigoni Margariti, Giannis S. Papaefstathiou, 2020

机译：通过集成在3D印刷装置中的CA-MOF改性碳浆电极的PB（II）的伏安测定
7. Pushing the limits of energetic materials - the synthesis and characterization of dihydroxylammonium 5,5'-bistetrazole-1,1'-diolate [O] . Fischer Niko, Fischer Dennis, Klapötke Thomas M., 2012

机译：推动高能材料的极限 - 二羟基铵5,5'-双四唑-1,1'-二醇的合成与表征
8. Theoretical Prediction of the Heats of Formation, Densities and Relative Sensitivities, and/or Synthetic Approaches Toward the Synthesis of High Energy Dense Materials (HEDMs): 3,5-Dinitro-1,3,5-Oxadiazinane, Bis-Adjacent RDX, Bis-Adjacent HMX, 4,4',6,6'-Tetranitro-1,1'-Bis(N-oxide)-5,5',6,6'-4H,4'H-5,5'-Bisimidazo Oxadiazole, and the Open-Cage Derivative of CL-20. [R] . Byrd, E. F., Sabatini, J. J. 2015

机译：形成热，密度和相对灵敏度的理论预测，和/或合成高能量密集材料（HEDms）的合成方法：3,5-二硝基-1,3,5-恶二唑烷，双相邻RDX，Bis - 相邻的HmX，4,4'，6,6'-四硝基-1,1'-双（N-氧化物）-5,5'，6,6'-4H，4'H-5,5'-双咪唑恶二唑和CL-20的开笼衍生物。

A novel 3D energetic MOF of high energy content: synthesis and superior explosive performance of a Pb(II) compound with 5,5 '-bistetrazole-1,1 '-diolate

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