syn-Bimane as a chelating O-donor ligand for palladium(II)

Das Partha Jyoti; Diskin-Posner Yael; Firer Michael; Montag Michael; Grynszpan Flavio

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syn-Bimane as a chelating O-donor ligand for palladium(II)

机译：顺丁烷作为钯（II）的螯合O-供体配体

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A cationic Pd(II) complex containing syn-(Me,Me)bimane as a ligand was prepared and fully characterized. This complex represents the first well-defined case of a bimane scaffold coordinated to a metal center. The strongly-fluorescent syn-bimane chelates the Pd(II) center via its carbonyl oxygen atoms, affording a non-fluorescent complex. The crystal structure of this complex shows that the coordinated bimane departs from planarity, with its bicyclic framework bent about the N-N bond. Spectroscopic evidence demonstrates that bimane coordination is reversible in solution.

机译：制备并充分表征了含有顺式（Me，Me）二manemane作为配体的阳离子Pd（II）配合物。该复合物代表了与金属中心相协调的双背支架的第一个明确定义的案例。强荧光的顺二马胺通过其羰基氧原子螯合Pd（II）中心，提供了一种非荧光络合物。该配合物的晶体结构表明，配位的双烯背离了平面性，其双环骨架围绕N-N键弯曲。光谱学证据表明，在解决方案中，双向反应是可逆的。

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《Dalton transactions: An international journal of inorganic chemistry》 |2016年第43期|共9页
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Das Partha Jyoti; Diskin-Posner Yael; Firer Michael; Montag Michael; Grynszpan Flavio;
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1. syn-Bimane as a chelating O-donor ligand for palladium(II) [J] . Das Partha Jyoti, Diskin-Posner Yael, Firer Michael, Dalton transactions: An international journal of inorganic chemistry . 2016,第43期

机译：顺丁烷作为钯（II）的螯合O-供体配体
2. Theoretical studies of molecular structure, electronic structure, spectroscopic properties and the ancillary ligand effect: A comparison of tris-chelate ML_3-type and ML_2X-type species for gallium(III) complexes with N,O-donor phenolic ligand, 2-(2-hydroxyphenyl) benzothiazole [J] . Tong Y.-P., Lin Y.-W. Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy . 2011,第2期

机译：分子结构，电子结构，光谱性质和辅助配体效应的理论研究：具有N，O-供体酚配体2-（2）的镓（III）配合物的三螯合物ML_3-型和ML_2X型物质的比较-羟苯基）苯并噻唑
3. New liquid crystalline materials based on ortho-metallated palladium(II) and platinum(II) complexes with S,O-donor CO-ligands [J] . Circu V, Ilis M, Dumitrascu F Journal of optoelectronics and advanced materials . 2008,第12期

机译：基于具有S，O供体CO配体的正金属化钯（II）和铂（II）配合物的新型液晶材料
4. Preparation of Pt(II)-Complexes with both C-N Chelate and Sulfur-rich S-S Chelate Ligands and Their Oxidation [C] . Yusuke Suga, Motohiro Nakano, Gen-etsu Matsubayashi Symposium on Organometallic Chemistry . 2004

机译：Pt（II）的制备 - 用C-N螯合物和富含硫的S-S螯合物配体及其氧化复用
5. I. Multicatalysis: Development of a Bismuth(III) triflate-catalyzed Nucleophilic addition/ Hydrofunctionalization Reaction in the Synthesis of Complex Heterocycles II. C--H Arylation of Arenes and Heteroarenes with Palladium-Carboxylate Catalysts: Identification of the Catalyst Resting State and the Crucial Role of Pivalate Ligand in Stabilization of the Catalyst III. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Importance of Phosphine Ligand for Basic Heteroarene Substrates IV. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Effect of the Properties of Basic Heteroarene Substrates on Direct Arylations. [D] . Tundel, Rachel E. 2011

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6. Bis26-bis(1H-pyrazol-1-yl)pyridinedecakis(μ2-3-nitrobenzoato)bis(3-nitrobenzoato)tetradysprosium(III): a linear tetranuclear dysprosium compound based on mixed N- and O-donor ligands [O] . Rong Hua, Xiao-Liu Wu, Jin-Ying Li 2014

机译：双26-双（1H-吡唑-1-基）吡啶癸基（μ2-3-硝基苯并）双（3-硝基苯并）四dy（III）：基于混合N-和O-的线性四核化合物供体配体
7. Cyclopalladation of the Indole Ring in Palladium(II) Complexes of 2N1O-Donor Ligands and Its Dependence on the O-Donor Properties [O] . -1

机译：2N1O-供体配体钯（II）络合物中吲哚环的环铝产物及其对O-供体性质的依赖性

syn-Bimane as a chelating O-donor ligand for palladium(II)

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