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Mechanical properties of poly(vinyl chloride) blends and corresponding graft copolymers

机译:聚氯乙烯共混物和相应的接枝共聚物的机械性能

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The mechanical properties of the poly(vinyl chloride) (PVC) and poly(glycidyl methacrylate) [poly(GMA)] blend system and the PVC and poly(hydroxyethyl methacrylate) [poly(HEMA)] blend system and their crosslinked films were investigated. At the same time, the mechanical properties for the corresponding graft copolymers such as PVC-g-GMA, PVC-g-HEMA, and their crosslinked films were also investigated in this study. The results showed that the tensile strengths for PVC-poly(GMA) blend systems were higher than those for PVC-g-GMA graft copolymer, and the tensile strengths for PVC-g-HEMA were higher than those for PVC-poly(HEMA) blend systems. However, the mechanical properties for the PVC-poly(GMA) blend system were not affected by the crosslinking of the blend system, but those for PVC-poly(HEMA) and their graft copolymers decreased with an increase of the equivalent ratio ([NCO]/[OH]) of the crosslinker. Finally, the surface hydrophilicity of the PVC-g-HEMA graft copolymer and PVC-poly(HEMA) blends were also assessed through measuring the contact angle. (C) 1998 John Wiley & Sons, Inc. [References: 24]
机译:研究了聚氯乙烯(PVC)和聚甲基丙烯酸缩水甘油酯[聚(GMA)]共混体系以及聚氯乙烯和聚甲基丙烯酸羟乙酯[聚(HEMA)]共混体系的机械性能及其交联膜。同时,本研究还研究了相应接枝共聚物(如PVC-g-GMA,PVC-g-HEMA及其交联膜)的机械性能。结果表明,PVC-poly(GMA)共混体系的抗张强度高于PVC-g-GMA接枝共聚物,而PVC-g-HEMA的抗张强度高于PVC-g(HEMA)混合系统。但是,PVC-聚(GMA)共混体系的机械性能不受共混体系的交联的影响,但是聚氯乙烯-聚(HEMA)及其接枝共聚物的机械性能随当量比的增加而降低([NCO ] / [OH])。最后,还通过测量接触角来评估PVC-g-HEMA接枝共聚物和PVC-聚(HEMA)共混物的表面亲水性。 (C)1998 John Wiley&Sons,Inc. [参考:24]

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