Mutual Diffusion and Phase Equilibrium in Copolymers of Nonyl Acrylate and Acrylic Acid-Diglycidyl Ether of Bisphenol A Systems

Mikhailov Yu M.; Ganina L.V.; Makhonina L.I.; Smirnov V.S.; Shapayeva N.V.

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Mutual Diffusion and Phase Equilibrium in Copolymers of Nonyl Acrylate and Acrylic Acid-Diglycidyl Ether of Bisphenol A Systems

机译：丙烯酸壬酯与双酚A体系丙烯酸-二缩水甘油醚的共聚物相互扩散和相平衡

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The influence of the composition of statistical copolymers of nonyl acrylate with acrylic acid on the rate of mass transfer and phase equilibrium in solutions with diglycidyl ether of bisphenol A was studied.For these systems,the data on concentration dependencies of mutual diffusion coeffcients and phase diagrams were obtained.The results were interpreted on the basis of the assumption about the effect of the effective concentration of nodes of the network of hydrogen bonds on the mutual diffusion and phase equilibrium.The dependencies of the mutual diffusion coefficients on the content of acrylic acid in the copolymers are described in terms of the free volume theory.

机译：研究了丙烯酸壬酯与丙烯酸统计共聚物的组成对双酚A二缩水甘油醚溶液中传质速率和相平衡的影响。对于这些系统，相互扩散系数的浓度依赖性数据和相图在假设氢键网络节点有效浓度对相互扩散和相平衡的影响的假设的基础上解释了结果。相互扩散系数与丙烯酸含量的相关性根据自由体积理论描述了共聚物。

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《Journal of Applied Polymer Science》 |1999年第10期|共4页
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Mikhailov Yu M.; Ganina L.V.; Makhonina L.I.; Smirnov V.S.; Shapayeva N.V.;
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phase equilibrium; copolymers of nonyl acrylate with acrylic acid; diglycidyl ether of bisphenol; network of hydrogen bonds; free volume theory;

机译：相平衡;丙烯酸壬酯与丙烯酸的共聚物;双酚的二缩水甘油醚;氢键网络;自由体积理论;

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1. Mutual Diffusion and Phase Equilibrium in Copolymers of Nonyl Acrylate and Acrylic Acid-Diglycidyl Ether of Bisphenol A Systems [J] . Mikhailov Yu M., Ganina L.V., Makhonina L.I., Journal of Applied Polymer Science . 1999,第10期

机译：丙烯酸壬酯与双酚A体系丙烯酸-二缩水甘油醚的共聚物相互扩散和相平衡
2. Phase Equilibrium and Diffusion in Binary Systems Based on Nonyl Acrylate, Acrylic Acid, and Their Homo- and Copolymers [J] . Yu. M. Mikhailov, L. V. Ganina, V. P. Roshchupkin Polymer science, Series B. Rapid communications reviews . 2007,第9a10期

机译：基于丙烯酸壬酯，丙烯酸及其均聚物和共聚物的二元体系的相平衡和扩散
3. Diffusion mobility of reactants, phase equilibrium, and specific features of radical copolymerization kinetics in the nonyl acrylate/2-methyl-5-vinyltetrazole system [J] . Mikhailov YM., Ganina LV., Kurmaz SV., Journal of Polymer Science, Part B. Polymer Physics . 2002,第13期

机译：丙烯酸壬酯/ 2-甲基-5-乙烯基四唑体系中反应物的扩散迁移率，相平衡和自由基共聚动力学的特定特征
4. Sol-Gel-Sol-Cloudy Transitions of Aqueous Solutions of Multi-Responsive Hydrophilic Diblock Copolymer Poly(methoxytri (ethylene glycol) acrylate-co-acrylic acid)-b-poly(ethoxydi(ethylene glycol) acrylate) [C] . Naixiong Jin, Jeremiah W. Woodcock, Chenming Xue Philadelphia, Pennsylvania Meeting . 2012

机译：多响应亲水二嵌段共聚物聚（甲氧基乙二醇（乙二醇）丙烯酸酯 - 共丙烯酸的水溶液的溶胶 - 溶胶 - 溶液溶液 - 聚（乙氧基（乙二醇）丙烯酸酯）
5. Studies on the crystalline structure and phase transition behavior of a perfectly alternating oligomeric poly(aryl ether ketone ketone) copolymer [D] . Honigfort, Paul Steven 2000

机译：完全交替的低聚聚（芳醚酮酮）共聚物的晶体结构和相变行为的研究
6. Phase Equilibrium and Interdiffusion in Poly(Vinyl Methyl Ether)-Water System [O] . Uliana V. Nikulova, Anatoly E. Chalykh 2020

机译：聚（乙烯基甲醚）水体系中的相平衡和相互扩离
7. Modificação de polímeros termorrígidos por separação de fases induzida por reação química: Sistema éter diglicidílico do Bisfenol-A e trietilenotetramina com copolímeros acrílicos Modification of thermosetting polymers by induced phase separation by chemical reaction: Diglycidyl ether of Bisphenol-A and triethylenetetramine with acrylic copolymers [O] . Garcia Filiberto González, Bluma G. Soares, Alessandra F. Neves, 2008

机译：通过化学反应诱导相分离改性热固性聚合物：双酚a的二缩水甘油醚和三亚乙基四胺与丙烯酸共聚物的改性热固性聚合物的改性热固性聚合物的改性热固性聚合物
8. Multifunctional Acrylic Ether Monomers, their Polymers, and Polymerizable EpoxideDerivatives from Simple Alpha-Substitution of Alkyl Acrylates [R] . Johnson, R. D., Mathias, L. J., Barclay, T. H. 1994

机译：多官能丙烯酸醚单体，它们的聚合物和可聚合的环氧化物衍生物来自简单的α-取代丙烯酸烷基酯

Mutual Diffusion and Phase Equilibrium in Copolymers of Nonyl Acrylate and Acrylic Acid-Diglycidyl Ether of Bisphenol A Systems

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