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Glass-transition temperature determination by microhardness in norbornene-ethylene copolymers

机译:降冰片烯-乙烯共聚物的显微硬度测定玻璃化转变温度

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Vickers microhardness as a function of temperature was determined in a series of norbornene-ethylene copolymers synthesized with a metallocene catalyst. The norbornene content in the samples ranges from 31 to 62 mol %, and all of them were found to be amorphous. The possibility of studying the glass-transition temperature by plotting the microhardness-temperature dependencies is discussed in addition to the limits and the reliability of the suggested method. Moreover, a linear dependency between microhardness at different temperatures and glass-transition temperature was established. (C) 2003 Wiley Periodicals, Inc. [References: 13]
机译:在一系列用茂金属催化剂合成的降冰片烯-乙烯共聚物中,测定了维氏显微硬度随温度的变化。样品中的降冰片烯含量为31〜62摩尔%,发现全部为非晶质。除了建议的方法的局限性和可靠性之外,还讨论了通过绘制显微硬度-温度依赖性来研究玻璃化转变温度的可能性。此外,建立了不同温度下的显微硬度与玻璃化转变温度之间的线性关系。 (C)2003 Wiley Periodicals,Inc. [参考:13]

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