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Reinforcement of natural rubber latex film by ultrafine calcium carbonate

机译:超细碳酸钙增强天然橡胶胶乳薄膜

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Using ultrafine calcium carbonate to reinforce natural rubber latex film, the effect of its content on latex properties such as surface tension, viscosity, mechanical stability, and heat stability and the physical properties of latex film before and after aging such as tear strength, modulus, and tensile strength were investigated. The results showed that the surface tension of natural rubber latex reinforced by ultrafine calcium carbonate only changed slightly; when the content of calcium carbonate was less than 20%, the change of viscosity was not obvious, but when the content was greater than 20%, the viscosity significantly lowered. Ultrafine calcium carbonate could effectively improve the tear strength, tensile strength, and modulus of the natural rubber latex film. The modulus increased with the increment of the calcium carbonate. When the content of calcium carbonate was less than 15%, the tear strength and tensile strength increased with the increments of calcium carbonate, but when the content was greater than 15%, the above-mentioned properties decreased with the increment of calcium carbonate. By comprehensive consideration, the best reinforcing effect was obtained at a content of 15% ultrafine calcium carbonate. The particle diameters of calcium carbonate and their distribution in the calcium carbonate emulsion and in the rubber film were analyzed with SEM and a laser particle size tester, which showed that the distribution of calcium carbonate in the latex film was even and that it could effectively reinforce natural rubber latex film. (C) 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 982-985, 2003. [References: 7]
机译:使用超细碳酸钙增强天然橡胶胶乳薄膜,其含量对胶乳性能的影响,如表面张力,粘度,机械稳定性和热稳定性,以及胶乳膜老化前后的物理性能,如撕裂强度,模量,和抗张强度进行了研究。结果表明,超细碳酸钙增强的天然橡胶胶乳的表面张力只有很小的变化。当碳酸钙的含量小于20%时,粘度的变化不明显,但是当碳酸钙的含量大于20%时,粘度显着降低。超细碳酸钙可以有效地改善天然橡胶胶乳薄膜的撕裂强度,拉伸强度和模量。模量随着碳酸钙的增加而增加。当碳酸钙的含量小于15%时,撕裂强度和拉伸强度随碳酸钙的增加而增加,但是当含量大于15%时,上述性能随碳酸钙的增加而降低。综合考虑,在15%的超细碳酸钙含量下可获得最佳的增强效果。用扫描电镜和激光粒度仪对碳酸钙的粒径及其在碳酸钙乳液和橡胶膜中的分布进行了分析,结果表明,乳胶膜中碳酸钙的分布均匀,可以有效地增强天然橡胶乳胶膜。 (C)2002 Wiley Periodicals,Inc. J Appl Polym Sci 87:982-985,2003。[参考:7]

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