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Swelling characterizations of chitosan and polyacrylonitrile semi-interpenetrating polymer network hydrogels

机译:壳聚糖和聚丙烯腈半互穿聚合物网络水凝胶的溶胀特性

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摘要

Temperature- and pH-responsive semi-interpenetrating polymer network (semi-IPN) hydrogels constructed with chitosan and polyacrylonitrile (PAN) were studied. The characterizations of semi-IPN hydrogels were investigated using Fourier transform infrared spectroscopy (FTIR) and differential scanning calorimetry (DSC). IPN hydrogels exhibited a relatively high swelling ratio, 23.31%-145.20% at room temperature. The swelling ratio of hydrogels depends on pH and temperature. DSC was used to determine the amount of free water in IPN hydrogels. The amount of free water increased with increasing chitosan content in the semi-IPN hydrogels. (C) 2003 Wiley Periodicals, Inc. [References: 23]
机译:研究了由壳聚糖和聚丙烯腈(PAN)构成的温度和pH响应的半互穿聚合物网络(semi-IPN)水凝胶。使用傅里叶变换红外光谱(FTIR)和差示扫描量热法(DSC)研究了半IPN水凝胶的表征。 IPN水凝胶在室温下具有相对较高的溶胀率,即23.31%-145.20%。水凝胶的溶胀率取决于pH和温度。 DSC用于确定IPN水凝胶中的游离水量。随着半IPN水凝胶中壳聚糖含量的增加,游离水的量也增加。 (C)2003 Wiley Periodicals,Inc. [参考:23]

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