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Phase-separation phenomena in the polymerization of styrene in the presence of polyethylene wax

机译:聚乙烯蜡存在下苯乙烯聚合中的相分离现象

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摘要

The demixing processes that occur during the polymerization of styrene in the presence of a low molar mass polyethylene wax were investigated. Quantitative information on the phase behavior of such a three-component system was obtained through the investigation of the temperature-induced phase separation and the observation of the phase separation during polymerization. Both techniques allow the construction of the same ternary phase diagram. Such phase behavior can be understood through the discussion of the interference of a liquid-liquid phase-separation process and crystallization. (C) 2003 Wiley Periodicals, Inc. [References: 15]
机译:研究了在低摩尔质量聚乙烯蜡存在下,苯乙烯聚合过程中发生的混合过程。通过研究温度引起的相分离和观察聚合过程中的相分离,可以获得有关这种三组分体系相行为的定量信息。两种技术都允许构造相同的三元相图。通过讨论液-液相分离过程和结晶的干扰,可以理解这种相行为。 (C)2003 Wiley Periodicals,Inc. [参考:15]

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