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Synthesis, characterization, and antibacterial activity of metal-containing polyurethanes

机译:含金属聚氨酯的合成,表征和抗菌活性

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Metal salts of mono(hydroxyethoxyethyl)-phthalate [M(HEEP)(2)] (M = Ca2+, Cd2+, and Pb2+) were synthesized by the reaction of diethylene glycol, phthalic anhydride, and metal acetates. A series of metal-containing polyurethanes (PUs) were synthesized by the reaction of hexamethylene diisocyanate or tolylene 2,4-diisocyanate with Ca2+, Cd2+, and Pb2+ salts of mono(hydroxyethoxy-ethyl)phthalate using di-n-butyltin dilaurate as a catalyst. The PUs were well characterized by FTIR, H-1, and C-13 NMR, solid-state C-13-CP-MAS NMR, viscosity, solubility, elemental, and X-ray diffraction studies. Thermal properties of the polymers were also studied by using thermogravimetric analysis and differential scanning calorimetry. The antibacterial activities of these polyurethanes have also been investigated by using the agar diffusion method. (C) 2003 Wiley Periodicals, Inc. [References: 36]
机译:通过二甘醇,邻苯二甲酸酐和乙酸金属盐的反应合成了邻苯二甲酸单(羟基乙氧基乙基)酯的金属盐[M(HEEP)(2)](M = Ca2 +,Cd2 +和Pb2 +)。六甲基二异氰酸酯或甲苯2,4-二异氰酸酯与单(羟基乙氧基-乙基)邻苯二甲酸酯的Ca2 +,Cd2 +和Pb2 +盐以二月桂酸二正丁基锡为反应物,合成了一系列含金属的聚氨酯(PU)。催化剂。通过FTIR,H-1和C-13 NMR,固态C-13-CP-MAS NMR,粘度,溶解度,元素和X射线衍射研究对PU进行了很好的表征。还通过使用热重分析和差示扫描量热法研究了聚合物的热性能。还通过使用琼脂扩散法研究了这些聚氨酯的抗菌活性。 (C)2003 Wiley Periodicals,Inc. [参考:36]

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