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Preparation and properties of a salt-resistant superabsorbent polymer

机译:耐盐超吸收性聚合物的制备与性能

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Crosslinked sodium polyacrylate was prepared by solution polymerization with N,N-methylene-bisacrylamide (bisAM) as crosslinking agent; it was subsequently surface-crosslinked by ethylene glycol diglycidyl ether (EGDE) and then was modified with inorganic salt to obtain a superabsorbent with water absorbency in 0.9 wt % NaCl aqueous solution at atmosphere and applied pressure (P approximate to 2 x 10(3) Pa) of 55 and 20 g.g(-1), respectively. Moreover, it also had excellent hydrogel strength. The effects of reaction temperature, reaction time, neutralization degree (ND) of acrylic acid, amount of initiator, crosslinking agent, and surface-crosslinking agent, mass ratio of inorganic salt to initial superabsorbent, molar ratio of sodium aluminate (NaAlO2) to potassium dihydrogen hyphosphate (KH2PO4) on water absorbency (WA) in 0.9 wt % NaCl aqueous, and the hydrogel modulus were investigated and optimized. (C) 2004 Wiley Periodicals, Inc.
机译:以N,N-亚甲基双丙烯酰胺(bisAM)为交联剂,通过溶液聚合制备聚丙烯酸钠交联剂。随后将其通过乙二醇二缩水甘油醚(EGDE)表面交联,然后用无机盐改性,从而在大气压和施加压力下于0.9 wt%NaCl水溶液中获得具有吸水率的超吸收剂(P约为2 x 10(3) Pa)分别为55和20 gg(-1)。此外,它还具有优异的水凝胶强度。反应温度,反应时间,丙烯酸的中和度(ND),引发剂,交联剂和表面交联剂的量,无机盐与初始超吸收剂的质量比,铝酸钠(NaAlO2)与钾的摩尔比的影响磷酸二氢钾(KH2PO4)在0.9 wt%NaCl水溶液中对吸水率(WA)的影响,并研究和优化了水凝胶模量。 (C)2004年Wiley Periodicals,Inc.

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