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首页> 外文期刊>Journal of Applied Polymer Science >Bulk conductive polymers prepared from nylon-6/6,9 copolymer/CuCl2 compounds
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Bulk conductive polymers prepared from nylon-6/6,9 copolymer/CuCl2 compounds

机译：由尼龙6 / 6,9共聚物/ CuCl2化合物制备的块状导电聚合物

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Semiconductive polymers were obtained by soaking nylon-6/6,9 particles in concentrated CuCl(2)(.)2H(2)O aqueous solutions, followed by reduction of the treated particles with sodium borohydride aqueous solutions. The reduced nylon-6/6,9/CuCl2 particles were compression molded at a relatively low temperature (160degreesC). The bulk volume resistivity obtained is at an intermediate level, similar to10(5) ohm-cm. The compounds generated by reduction of the nylon-6/6,9/CuCl2 particles were determined to consist of metallic copper by means of energy-dispersive X-ray micro-analysis. The metallic copper is responsible for the electrical conductivity of the bulk samples. Samples stored at the ambient atmosphere gradually absorb oxygen and moisture, resulting in a decrease in the conductivity. The morphology of nylon-6/6,9/CuCl2 samples before and after reduction was studied by a scanning electron microscope and transmission electron microscope. A two-level hierarchy structure, submicrometer and nano-sized, of copper particles was observed, forming the conducting copper networks. Molded samples of reduced nylon-6/CuCl2 and nylon-6,6/CuCl2 particles, prepared by the same procedure as that of nylon-6/6,9/CuCl2 particles, were insulating, whereas a reduced nylon-6/CuCl2 film was moderately conductive. (C) 2004 Wiley Periodicals, Inc. [References: 15]
机译：通过将尼龙6 / 6,9颗粒浸泡在浓CuCl（2）（。）2H（2）O水溶液中，然后用硼氢化钠水溶液还原处理过的颗粒，从而获得半导体聚合物。将还原的尼龙-6 / 6，9 / CuCl 2颗粒在相对较低的温度（160℃）下压塑。所获得的体积电阻率处于中等水平，类似于10（5）ohm-cm。通过能量色散X射线微分析确定通过还原尼龙-6 / 6,9 / CuCl2颗粒产生的化合物由金属铜组成。金属铜负责大块样品的电导率。存储在环境大气中的样品逐渐吸收氧气和水分，导致电导率降低。用扫描电子显微镜和透射电子显微镜研究了尼龙-6 / 6,9 / CuCl2样品还原前后的形貌。观察到铜粒子的亚微米级和纳米级两级结构，形成了导电铜网络。按照与尼龙-6 / 6,9 / CuCl2颗粒相同的步骤制备的尼龙-6 / CuCl2和尼龙-6,6 / CuCl2颗粒还原的模制样品是绝缘的，而尼龙-6 / CuCl2还原膜则是绝缘的适度导电。 （C）2004 Wiley Periodicals，Inc. [参考：15]

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