首页> 外文期刊>Journal of Applied Polymer Science >The straight-chain segment length distribution in xerogels of UHMWPE, which provide high drawability of gel-derived fibers
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The straight-chain segment length distribution in xerogels of UHMWPE, which provide high drawability of gel-derived fibers

机译:超高分子量聚乙烯干凝胶中的直链链段长度分布,可提供凝胶衍生纤维的高拉伸性

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摘要

A series of ultra-high-molecular-weight reactor powders with different technological prehistory were utilized for obtaining fibers through the gel technology. The fibers prepared from some powders exhibited high draw ratios and good mechanical properties (Young's modulus and tensile stress) but other powders yielded fibers of very low drawability. The low-frequency Raman study revealed that the straight-chain-segment (SCS) length distributions in dried gels prepared from powders of "drawable" group are bimodal, while the gels issued from powders unsuitable for fiber drawing have unimodal length distributions of SCS. (C) 2007 Wiley Periodicals, Inc.
机译:利用一系列具有不同技术史的超高分子量反应器粉末,通过凝胶技术获得了纤维。由某些粉末制得的纤维表现出高拉伸比和良好的机械性能(杨氏模量和拉伸应力),但其他粉末制得的纤维的拉伸性极低。低频拉曼研究表明,由“可拉伸”组粉末制备的干凝胶中的直链段(SCS)长度分布是双峰的,而不适用于纤维拉伸的粉末所散发的凝胶具有SCS的单峰长度分布。 (C)2007 Wiley期刊公司

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