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Microstructure dependent properties of polypropylene-clay nanocomposites

机译:聚丙烯粘土纳米复合材料的微观结构依赖性

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The mechanical properties of melt processed polypropylene-montmorillonite nanocomposites were studied as a function of clay content. The measurement of tensile properties at room temperature and dynamic mechanical properties over a wide temperature range reveal a decrease in modulus and tensile strength of the composite with increasing clay content. The origins of this anomalous result were examined in detail using X-ray diffraction and differential scanning calorimeter, which averaged the microstructure over reasonable specimen volumes. Micromechanical models could be used to adequately describe the composite properties, provided appropriate properties for the matrix and particle were used. The matrix properties were found to affect the average properties significantly. (C) 2006 Wiley Periodicals, Inc. J AppI Polym Sci 103:204-210,2007
机译:研究了熔融加工的聚丙烯-蒙脱土纳米复合材料的机械性能与粘土含量的关系。在室温下的拉伸性能和在宽温度范围内的动态力学性能的测量表明,随着粘土含量的增加,复合材料的模量和拉伸强度降低。使用X射线衍射和差示扫描量热仪详细检查了这种异常结果的起源,该方法对合理的样品体积内的平均显微组织进行了平均。可以使用微力学模型来充分描述复合材料的性能,前提是要使用适当的基质和颗粒性能。发现基质性质显着影响平均性质。 (C)2006 Wiley Periodicals,Inc. J AppI Polym Sci 103:204-210,2007

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