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Alkaline hydrolysis of methyl acrylate grafted cellulose fibers

机译:丙烯酸甲酯接枝纤维素纤维的碱水解

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In this work, methyl acrylate grafted cellulose fibers were hydrolyzed in an aqueous NaOH solution to obtain a superabsorbent hydrogel. The effect of process variables, such as the hydrolysis reaction time, temperature, and NaOH concentration, during alkaline hydrolysis were carefully determined and optimized. The degree of hydrolysis was estimated on the basis of the determination of the carboxylate group contents. The material loss during hydrolysis followed a first-order reaction mechanism. The differences in the behavior of the grafted fibers during hydrolysis could be explained by their structural differences. (C) 2007 Wiley Periodicals, Inc.
机译:在这项工作中,将丙烯酸甲酯接枝的纤维素纤维在NaOH水溶液中水解,以获得超吸收性水凝胶。仔细确定和优化了过程变量(如水解反应时间,温度和NaOH浓度)对碱水解的影响。水解度基于羧酸根含量的测定来估计。水解过程中的材料损失遵循一级反应机理。接枝纤维在水解过程中的行为差异可以通过其结构差异来解释。 (C)2007 Wiley期刊公司

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