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Mechanical properties and thermal stability of poly(L-lactide)/calcium carbonate composites

机译:聚(L-丙交酯)/碳酸钙复合材料的力学性能和热稳定性

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摘要

Poly(L-lactide) (PLA) was melt-mixed with micrometer-sized and nanosized calcium carbonate (CaCO3) particles before and after modification with calcium stearate. Adhesion between the CaCO3 particles and the PLA matrix was assessed qualitatively by scanning electron microscopy observation of the fractured surface morphology of the composites. The effect of the incorporation of the CaCO3 particles on the thermal stability of the PLA-based composites was quantified by the temperatures corresponding to 5 and 50% of weight loss and the activation energy determined through thermogravimetric analyses of the composites. The tensile strength and modulus values of the composite were improved greatly without a significant loss in the elongation at break when the nanosized CaCO3 was incorporated up to 30 wt %. (c) 2008 Wiley Periodicals, Inc.
机译:在用硬脂酸钙改性之前和之后,将聚(L-丙交酯)(PLA)与微米级和纳米级碳酸钙(CaCO3)颗粒熔融混合。通过扫描电子显微镜观察复合材料的断裂表面形态,定性地评估了CaCO3颗粒与PLA基质之间的附着力。通过对应于重量损失的5%和50%的温度以及通过复合材料的热重分析确定的活化能来量化CaCO3颗粒的掺入对PLA基复合材料的热稳定性的影响。当掺入至多30wt%的纳米级CaCO 3时,复合材料的拉伸强度和模量值得到了极大的改善,而断裂伸长率没有明显损失。 (c)2008年Wiley Periodicals,Inc.

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