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Effect of vinyl acetate content on the mechanical and thermal properties of ethylene vinyl acetate/MgAl layered double hydroxide nanocomposites

机译:醋酸乙烯酯含量对乙烯醋酸乙烯酯/ MgAl层状双氢氧化物纳米复合材料力学性能和热性能的影响

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摘要

Ethylene vinyl acetate (EVA)/Mg-Al layered double hydroxide (LDH) nanocomposites using EVA of different vinyl acetate contents (EVA-18 and EVA-45) have been prepared by solution blending method. X-ray diffraction and transmission electron microscopic studies of nanocomposites clearly indicate the formation of exfoliated/intercalated structure for EVA-18 and completely delaminated structure for EVA-45. Though EVA-18 nanocomposites do not show significant improvement in mechanical properties, EVA-45 nanocomposites with 5 wt % DS-LDH content results in tensile strength and elongation at break to be 25% and 7.5% higher compared to neat EVA-45. The data from thermogravimetric analysis show that the nanocomposites of EVA-18 and EVA-45 have approximate to 10 degrees C higher thermal decomposition temperature compared to neat EVA. (c) 2008 Wiley Periodicals, Inc.
机译:通过溶液共混法制备了使用不同醋酸乙烯酯含量的EVA(EVA-18和EVA-45)的乙烯醋酸乙烯酯(EVA)/ Mg-Al层状双氢氧化物(LDH)纳米复合材料。纳米复合材料的X射线衍射和透射电子显微镜研究清楚地表明,EVA-18的剥离/插层结构的形成以及EVA-45的完全分层结构的形成。尽管EVA-18纳米复合材料的机械性能没有显着改善,但DS-LDH含量为5 wt%的EVA-45纳米复合材料的拉伸强度和断裂伸长率比纯EVA-45高25%和7.5%。来自热重分析的数据表明,与纯EVA相比,EVA-18和EVA-45的纳米复合材料的热分解温度高约10摄氏度。 (c)2008年Wiley Periodicals,Inc.

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