Ruthenium (II) complexes immobilized on swellable polyacrylate matrices: synthesis and catalytic applications

Liu ZS; Rempel GL

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Ruthenium (II) complexes immobilized on swellable polyacrylate matrices: synthesis and catalytic applications

机译：固定在可溶胀聚丙烯酸酯基质上的钌（II）配合物：合成和催化应用

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RuH2(PPh3)(4) has been immobilized on swellable polyacrylate matrices to provide heterogenized carboxylate-derivatives. These swellable polymer supported ruthenium (II) complex catalysts have been used in the transfer hydrogenation of aldehydes. Hydrogen donors are formate salt, cyclohexanol, and benzyl alcohol. The catalysts exhibit good activity for hydrogen transfer reduction of aldehydes. (C) 2008 Wiley Periodicals, Inc.

机译：RuH2（PPh3）（4）已固定在可溶胀的聚丙烯酸酯基质上，以提供杂化的羧酸酯衍生物。这些可溶胀的聚合物负载的钌（II）络合物催化剂已用于醛的转移加氢。氢供体是甲酸盐，环己醇和苯甲醇。该催化剂对醛的氢转移还原表现出良好的活性。（C）2008 Wiley期刊公司

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《Journal of Applied Polymer Science》 |2008年第5期|共8页
作者
Liu ZS; Rempel GL;
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ruthenium; swellable polyacrylate matrices; hydrogen transfer hydrogenation; aldehyde; hydrogen donor; AQUEOUS SODIUM FORMATE; SUPERABSORBENT POLYMERS; TRANSFER HYDROGENATION; AROMATIC-ALDEHYDES; SWELLING BEHAVIOR; REDUCTION; RHODIUM;

机译：钌;可溶聚丙烯酸酯基质;氢转移加氢;醛;给氢体;甲酸钠水溶液;超吸收性聚合物;转移加氢;芳族醛;溶胀行为;还原;铑;

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1. Ruthenium (II) complexes immobilized on swellable polyacrylate matrices: synthesis and catalytic applications [J] . Liu ZS, Rempel GL Journal of Applied Polymer Science . 2008,第5期

机译：固定在可溶胀聚丙烯酸酯基质上的钌（II）配合物：合成和催化应用
2. Synthesis of iron(II), manganese(II), cobalt(II) and ruthenium(II) complexes containing tridentate nitrogen ligands and their application in the catalytic oxidation of alkanes [J] . Britovsek GJP, England J, Spitzmesser SK, Dalton transactions: An international journal of inorganic chemistry . 2005,第5期

机译：含三齿氮配体的铁（II），锰（II），钴（II）和钌（II）配合物的合成及其在烷烃催化氧化中的应用
3. Hydrogen transfer from cyclohexanol to aromatic aldehydes catalyzed by heterogenized ruthenium(II)complexes bound to swellable polymer matrices [J] . Z.S.Liu, G.L.Rempel Chemical engineering journal . 2009,第2a3期

机译：氢键合到可溶胀聚合物基质上的异质钌（II）络合物催化氢从环己醇转移到芳族醛
4. Immobilized Cu (II)—Amino Acid Complexes asProspective Highly Efficient Catalytic Materials:Synthesis, Structural Characterization andCatalytic Activities [C] . Istvan Palinko, Adrien Ordasi, Janos T. Kiss, International Conference on Perspectives in Vibrational Spectroscopy . 2008

机译：固定化Cu（II） - 氨基酸复合物表现出高效催化材料：合成，结构表征和催化活性
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机译：新型和固定化钯和钌配合物的合成，表征和催化应用。
6. Arene–Ruthenium(II) Complexes Containing 11H-Indeno12-bquinoxalin-11-oneDerivatives and Tryptanthrin-6-oxime: Synthesis CharacterizationCytotoxicity and Catalytic Transfer Hydrogenation of Aryl Ketones [O] . VladislavaV. Matveevskaya, Dmitry I. Pavlov, Taisiya S. Sukhikh, 2020

机译：含11H-茚并12-b喹喔啉-11-一的芳烃-钌（II）配合物衍生物和Tryptanthrin-6-肟：合成表征芳基酮的细胞毒性和催化转移加氢
7. Synthesis and catalytic applications of ruthenium(ii)-phosphino-oxime complexes [O] . Francos Arias, Javier, Menéndez Rodríguez, Lucía, Tomás González de Mendivil, Eder, 2016

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Ruthenium (II) complexes immobilized on swellable polyacrylate matrices: synthesis and catalytic applications

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