mu-gels as support materials for dinuclear olefin polymerization catalysts

Schilling M; Gorl C; Alt HG

首页> 外文期刊>Journal of Applied Polymer Science >mu-gels as support materials for dinuclear olefin polymerization catalysts

【24h】

mu-gels as support materials for dinuclear olefin polymerization catalysts

机译：mu-gel作为双核烯烃聚合催化剂的载体材料

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

mu-Gels which consist of poly(organosilicon) networks can be employed as efficient support materials for ethylene polymerization catalyst precursors. Alkylaluminum cocatalysts can be fixed on the mu-gel surfaces using the PHT ("partially hydrolyzed trimethylaluminum") method. The influence of different aluminum/water ratios on the ethylene polymerization properties of these heterogeneous systems is investigated. Dinuclear silicon bridged zirconium complexes are used as catalyst precursors yielding polyethylenes with broad or bimodal molecular weight distributions. (C) 2008 Wiley Periodicals, Inc.

机译：由聚（有机硅）网络组成的mu-Gel可用作乙烯聚合催化剂前体的有效载体材料。烷基铝助催化剂可以使用PHT（“部分水解的三甲基铝”）方法固定在mu-gel表面。研究了不同铝/水比例对这些非均相体系乙烯聚合性能的影响。双核硅桥联的锆络合物用作催化剂前体，产生具有宽或双峰分子量分布的聚乙烯。（C）2008 Wiley期刊公司

著录项

来源
《Journal of Applied Polymer Science》 |2008年第5期|共11页
作者
Schilling M; Gorl C; Alt HG;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
metallocene complexes; mu-gels; heterogeneous catalysts; ethylene polymerization; polyethylene; ANSA ZIRCONOCENE COMPLEXES; ETHYLENE POLYMERIZATION; METALLOCENE CATALYSTS; METHYLALUMINOXANE MAO; TERT-BUTYLALUMINUM; SITE CATALYSTS; ALPHA-OLEFINS; SILICA; METHYLALUMOXANE; COCATALYSTS;

机译：茂金属配合物;凝胶;非均相催化剂;乙烯聚合;聚乙烯;ANSA锆茂络合物;乙烯聚合;茂金属催化剂;甲基硅铝氧烷毛;叔丁基铝铝;现场催化剂;烯烃-烯烃;二氧化硅;甲醇;

相似文献

外文文献
中文文献
专利

1. mu-gels as support materials for dinuclear olefin polymerization catalysts [J] . Schilling M, Gorl C, Alt HG Journal of Applied Polymer Science . 2008,第5期

机译：mu-gel作为双核烯烃聚合催化剂的载体材料
2. mu-gels as support materials for dinuclear olefin polymerization catalysts [J] . Schilling M, Gorl C, Alt HG Journal of Applied Polymer Science . 2008,第5期

机译：mu-gel作为双核烯烃聚合催化剂的载体材料
3. Nanostructured Materials As Catalyst Supports in Olefin Polymerization [J] . Leyla Jaramillo Zapata, Bernardo Herrera Munera, Karen Paola Cacua Madero, Nanotechnology research journal . 2015,第2期

机译：纳米结构材料作为烯烃聚合反应的催化剂
4. Synthesis of Dinuclear Complexes by Olefin Metathesis and their Utilization as Polymerization Catalyst [C] . Junpei Kuwabara, Daisuke Takeuchi, Kohtaro Osakada Symposium on Organometallic Chemistry . 2003

机译：烯烃复分解的二维配合物合成及其利用作为聚合催化剂
5. Influence of supports on gas-phase olefin polymerization over polymer-supported (n-BuCp)2-zirconium chloride/MAO catalysts. [D] . Hammawa, Hassan. 2004

机译：在聚合物负载的（n-BuCp）2-氯化锆/ MAO催化剂上，载体对气相烯烃聚合的影响。
6. Homo-polymerization of α-Olefins and Co-polymerization of Higher α-Olefins with Ethylene in the Presence of CpTiCl2(OC6H4X-p)/MAO Catalysts (X = CH3 Cl) [O] . W. Skupinski, K. Nicinski, D. Jamanek, 2005

机译：在CpTiCl2（OC6H4X-p）/ MAO催化剂（X = CH3Cl）存在下α-烯烃的均聚和高级α-烯烃与乙烯的共聚
7. High-Throughput Synthesis of Support Materials for Olefin Polymerization Catalyst [O] . -1

机译：烯烃聚合催化剂载体高通量合成

mu-gels as support materials for dinuclear olefin polymerization catalysts

摘要

著录项

相似文献

相关主题

期刊订阅