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Diametric Swelling and Hydrophilic Characteristics of Fibrous Acrylic Ion Exchanger

机译:纤维状丙烯酸离子交换剂的直径膨胀和亲水特性

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摘要

In our previous works, modified acrylic fiber samples with highly ion-exchange ability were described. These fibers contain Suitable functional groups such as amidoxime, amid, and amine groups in their molecular chains. In this work, swelling in fiber diameter and hydrophilic properties of the modified acrylic fiber samples, as important parameters affecting on ion-exchange efficiency, were investigated. The results showed that all modification treatments gave rise to diameter swelling ratio, but this does not mean that sample with highest swelling ratio in all cases can result in highest ability to ion-exchange. In other words, the relation between them was complicated, and several factors such as the kind and the size of ion adsorbent and crosslinking ability of chemical reagent were used for modification interfere in ion-exchange phenomena. The results of moisture adsorption indicate that incorporating functional groups by modification treatments enhance moisture adsorption in which samples with higher ion-exchange ability possess higher hydrophilic property. (C) 2008 Wiley Periodicals, Inc. J Appl Polym Sci 110: 3843-3847, 2008
机译:在我们以前的工作中,描述了具有高离子交换能力的改性丙烯酸纤维样品。这些纤维在其分子链中包含合适的官能团,例如a胺肟,酰胺基和胺基。在这项工作中,作为影响离子交换效率的重要参数,研究了改性丙烯酸纤维样品的纤维直径膨胀和亲水性能。结果表明,所有改性处理均会提高直径溶胀率,但这并不意味着在所有情况下具有最高溶胀率的样品都可以具有最高的离子交换能力。换句话说,它们之间的关系是复杂的,并且使用诸如离子吸附剂的种类和大小以及化学试剂的交联能力等多种因素来进行改性会干扰离子交换现象。水分吸附的结果表明,通过改性处理并入官能团可增强水分吸附,其中具有较高离子交换能力的样品具有较高的亲水性。 (C)2008 Wiley Periodicals,Inc. J Appl Polym Sci 110:3843-3847,2008

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