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Anticorrosive Properties of Epoxy Resin Coatings Cured by Aniline/p-Phenylenediamine Copolymer

机译:苯胺/对苯二胺共聚物固化的环氧树脂涂料的防腐性能

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摘要

Aniline/p-phenylenediamine copolymer [poly(ANI-co-p-PDA)] was prepared by chemical oxidative polymerization. FTIR and 1H-NMR analysis indicate that the poly(ANI-co-p-PDA) is oligomer with end-capped amino groups, which can cure epoxy resin. The anticorrosion performance of carbon steel (CS) samples coated by epoxy resin coating cured with poly(ANI-co-p-PDA) and epoxy resin coating cured with triethylenetetramine exposed to 5 wt % NaCl and 0.1 mol/L HCl aqueous solution is studied by the potentiodynamic polarization and electrochemical impedance spectroscopy. The results show that the CS coated by epoxy resin coating cured with poly (ANI-co-p-PDA) has more excellent corrosion protection than that of epoxy resin coating cured with triethylenetetramine. Raman spectroscopy analysis indicates that the surface of CS coated by epoxy resin coating cured with poly(ANI-co-p-PDA) forms passive layer, which is composed of a-Fe2O3.
机译:通过化学氧化聚合制备苯胺/对苯二胺共聚物[聚(ANI-co-p-PDA)]。 FTIR和1H-NMR分析表明,聚(ANI-co-p-PDA)是具有封端氨基的低聚物,可以固化环氧树脂。研究了用聚(ANI-co-p-PDA)固化的环氧树脂涂层和暴露于5 wt%NaCl和0.1 mol / L HCl水溶液的三亚乙基四胺固化的环氧树脂涂层对碳钢(CS)样品的防腐性能通过电位动力学极化和电化学阻抗谱。结果表明,用聚(ANI-co-p-PDA)固化的环氧树脂涂层的CS涂层比用三亚乙基四胺固化的环氧树脂涂层的CS具有更好的防腐性能。拉曼光谱分析表明,由聚(ANI-co-p-PDA)固化的环氧树脂涂层的CS涂层表面形成由a-Fe2O3组成的钝化层。

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