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Transparent Conducting Films Based on Nanofibrous Polymeric Membranes and Single-Walled Carbon Nanotubes

机译:基于纳米纤维聚合物膜和单壁碳纳米管的透明导电膜

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摘要

Transparent and electrically conducting films were fabricated using a novel and simple method in which single-walled carbon nanotubes (SWCNTs) adsorbed onto bacterial cellulose membranes were embedded into a transparent polymer resin. The bacterial cellulose membranes consisting of numerous nanofibrils were found to play important roles in this process. The bacterial cellulose membranes impart optical transparency to the nanocomposites due to the size of the materials during the synthesis of the nanocomposite using a transparent polymer resin. The membranes play a secondary role as a template for depositing uniformly dispersed SWCNTs. This results in not only electrically conducting pathways but also prevents interference from the transmittance of optically transparent nanocomposites. Transparent conducting films with a wide range of transmittances and surface resistances could be obtained by controlling the immersion time and SWCNT concentration in the SWCNT dispersions. A transparent conducting film with a transmittance and surface resistance of 77.1% at 550 ran and 2.8 k Omega/sq, respectively, was fabricated from a 0.01 wt %. SWCNT dispersion for an immersion time of 3 h. In addition, the transparent conducting films were quite flexible and maintained their properties even after crumpling.
机译:使用新颖且简单的方法制造透明导电膜,其中将吸附在细菌纤维素膜上的单壁碳纳米管(SWCNT)嵌入透明聚合物树脂中。发现由许多纳米原纤维组成的细菌纤维素膜在该过程中起重要作用。由于在使用透明聚合物树脂合成纳米复合材料的过程中材料的尺寸,细菌纤维素膜使纳米复合材料具有光学透明性。该膜在沉积均匀分散的SWCNT的模板方面起着次要作用。这不仅导致导电路径,而且防止了来自光学透明纳米复合材料的透射率的干扰。通过控制SWCNT分散液中的浸渍时间和SWCNT浓度,可以获得具有宽范围透射率和表面电阻的透明导电膜。由0.01重量%制成透明导电膜,其在550nm和2.8kΩ/ sq下分别具有77.1%的透射率和表面电阻。将SWCNT分散3个小时。另外,透明导电膜非常柔软并且即使在起皱之后也保持其性能。

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