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Synthesis and Characterization of Bis(4-cyanato-3,5- dimethylphenyl)anisylmethane/Epoxy/Glass Fiber Composites

机译:双(4-氰基-3,5-二甲基苯基)茴香基甲烷/环氧/玻璃纤维复合材料的合成与表征

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摘要

Bis(4-cyanato-3,5-dimethylphenyl)anisylmethane was prepared by treating CNBr with bis(4-hydroxy- 3,5-dimethylphenyl)anisylmethane and blended with commercial epoxy resin in different ratios and cured at 120 C for 2 h, 180 C for 1 h, and postcured at 220 C for 1 h using diamino diphenyl methane as curing agent. Castings of neat resin and blends were prepared and characterized. The composite laminates were also fabricated with glass fiber using the same composition. The tensile strength of the composites increased with increase in cyanate content (3, 6, and 9%) from 322 to 355 MPa. The fracture toughness values also increased from 0.7671 kJ/m2, for neat epoxy resin, to 0.8615 kJ/m2, for 9% cyanate ester-modified epoxy system. The 10% weight loss temperature of pure epoxy (358 C) was increased to 390 C by the incorporation of cyanate ester resin. The incorporation of cyanate ester up to 9% in the epoxy resin increases the Tg from 143 to 147 C.
机译:通过用双(4-羟基-3,5-二甲基苯基)茴香基甲烷处理CNBr制备双(4-氰基-3,5-二甲基苯基)茴香基甲烷,并以不同比例与市售环氧树脂共混并在120°C下固化2小时, 180℃加热1小时,然后使用二氨基二苯甲烷作为固化剂在220℃后固化1小时。制备并表征了纯树脂和共混物的铸件。复合层压板也使用相同的组成由玻璃纤维制成。复合材料的拉伸强度随着氰酸盐含量(3%,6%和9%)从322 MPa增加到355 MPa而增加。断裂韧性值也从纯环氧树脂的0.7671 kJ / m2增加到9%氰酸酯改性的环氧树脂体系的0.8615 kJ / m2。通过引入氰酸酯树脂,将纯环氧树脂的10%失重温度(358 C)提高到390C。在环氧树脂中最多加入9%的氰酸酯会使Tg从143°C增加到147°C。

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