• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Journal of Applied Polymer Science >Properties of a Poly(acrylamide-co-diallyl dimethyl ammonium chloride) Hydrogel Synthesized in a Water-Ionic Liquid Binary System
【24h】

Properties of a Poly(acrylamide-co-diallyl dimethyl ammonium chloride) Hydrogel Synthesized in a Water-Ionic Liquid Binary System

机译：水离子液体二元体系合成的聚丙烯酰胺-共二烯丙基二甲基氯化铵水凝胶的性质

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

A novel copolymer hydrogel, poly(acrylamide-co-diallyl dimethyl ammonium chloride), was prepared by the radical copolymerization of acrylamide and diallyl dimethyl ammonium chloride in an ionic liquid (IL)-water binary system in the presence of the crosslinker N,N'-methylene bisacrylamide. The equilibrium swelling ratios of the hydrogels synthesized in the M-water binary system increased with the content of IL and were remarkably higher than that of the gel synthesized in water. Differential scanning calorimetry measurements showed that the glass-transition temperatures of the dry hydrogels that were synthesized in the IL-water binary system were remarkably lower than that of the gel synthesized in pure water. The mechanical properties of the gels synthesized in both water and the IL-water binary system were characterized with a universal material-testing machine. The results show that fracture toughness of the hydrogels was improved when they were synthesized in the IL-water binary system. The gel shrank under a direct-current electric field. The response rates of the gels that were synthesized with the IL-water binary system were faster than that of the gel synthesized in water.
机译：在交联剂N，N存在下，通过离子液体（IL）-水二元体系中丙烯酰胺和二烯丙基二甲基氯化铵的自由基共聚反应，制备了一种新型的共聚物水凝胶聚（丙烯酰胺-共二烯丙基二甲基氯化铵）。 '-亚甲基双丙烯酰胺。 M-水二元体系中合成的水凝胶的平衡溶胀率随IL含量的增加而增加，并且显着高于水中合成的凝胶。差示扫描量热法测量表明，在IL-水二元体系中合成的干燥​​水凝胶的玻璃化转变温度明显低于在纯水中合成的凝胶的玻璃化转变温度。用通用材料测试机表征了在水和IL-水二元系统中合成的凝胶的机械性能。结果表明，在IL-水二元体系中合成水凝胶时，其断裂韧性得到改善。凝胶在直流电场下收缩。用IL-水二元系统合成的凝胶的响应速率要快于在水中合成的凝胶的响应速率。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号