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首页> 外文期刊>Journal of Applied Polymer Science >Synthesis of biodegradable amino-acid-based poly(ester amide)s and poly(ether ester amide)s with pendant functional groups
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Synthesis of biodegradable amino-acid-based poly(ester amide)s and poly(ether ester amide)s with pendant functional groups

机译：具有侧基官能团的可生物降解的氨基酸基聚（酯酰胺）和聚（醚酯酰胺）的合成

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摘要

A new family of biodegradable amino-acidbased poly(ester amide)s (AA-PEAs) and amino-acidbased poly(ether ester amide)s (AA-PEEAs) consisting of reactive pendant functional groups (ACOOH or ANH_2) were synthesized from unsaturated AA-PEAs and AA-PEEAs via a thiol-ene reaction in the presence of a radical initiator (2,2'-azobisisobutyronitrile). The synthetic method was a one-step reaction with near 100% yields under mild reaction conditions. The resulting functional AA-PEA and AA-PEEA polymers were characterized by Fourier transform infrared spectroscopy, NMR, and differential scanning calorimetry. These new functional AA-PEA and AA-PEEA derivatives had lower glass-transition temperatures than the original unsaturated AA-PEA and AA-PEEA polymers, and their solubility in some organic solvents also improved.
机译：由不饱和分子合成了一个新的可生物降解的氨基酸基聚酯酰胺（AA-PEAs）和氨基酸基聚醚酯酰胺（AA-PEEAs）。在自由基引发剂（2,2'-偶氮二异丁腈）存在下，通过硫醇-烯反应进行的AA-PEA和AA-PEEA。合成方法为一步反应，在温和的反应条件下收率接近100％。通过傅立叶变换红外光谱，NMR和差示扫描量热法对所得的功能性AA-PEA和AA-PEEA聚合物进行表征。这些新的功能性AA-PEA和AA-PEEA衍生物的玻璃化温度低于原始的不饱和AA-PEA和AA-PEEA聚合物，并且它们在某些有机溶剂中的溶解度也得到了改善。

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